Synthesis and characterization of 3-allyl-5,5-dimethylhydantoin

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Abstract

Bonding agent is functional component to improve mechanical properties of solid propellant. A new bonding agent, 3-allyl-5,5-dimethylhydantoin ADMH) was synthesized by the Gabriel method. The condition of the reaction was n(DMH): (allylbromine): (methyl alcohol solvent of KOH) =1:1:1, and water was used as solvent. The yield of ADMH is 50% and its purity is 99.97%. Chemical structure of ADMH was identified by TG-DTA, UV, NMR, FT-IR and MS etc. Melting point of ADMH is 65-66°C and its decomposition temperature is 168.3 °C.

Original languageEnglish
Pages (from-to)19-22
Number of pages4
JournalHanneng Cailiao/Chinese Journal of Energetic Materials
Volume17
Issue number1
Publication statusPublished - Feb 2009

Keywords

  • 5,5-dimethylhydantoin
  • Gabriel
  • Organic chemistry
  • Synthesis

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