Synthesis and application on UV-curable epoxy/ dendritic maleate resin

Linya Zhang; Qingze Jiao; Yun Zhao; Mingji Zhou; Wei Feng; Yanrui Ge

doi:10.1007/s00289-011-0503-2

Synthesis and application on UV-curable epoxy/ dendritic maleate resin

Linya Zhang, Qingze Jiao^*, Yun Zhao, Mingji Zhou, Wei Feng, Yanrui Ge

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The dendritic polyester, dendritic maleate, and epoxy/dendritic maleate resins were synthesized and analyzed by acid value, hydroxyl value, FT-IR, TGA, and DSC. The dendritic maleate and epoxy/dendritic maleate resins were applied in UV-curable coating, and the properties of the UV-curable coatings were compared. With the introduction of epoxy resin, the epoxy/dendritic maleate resin formed larger cross linked structure and more cavities which helped to improve the properties of coating. The epoxy/dendritic maleate resin exhibited higher thermal decomposition temperature and T _g. The coating based on equal content of epoxy resin and dendritic maleate had higher gel content and better properties such as impact strength, adhesive strength, flexibility, pencil hardness, and solvent resistances. The SEM figures showed that the epoxy/dendritic maleate resin could form more cavities and improve the toughness of coating.

Original language	English
Pages (from-to)	1583-1594
Number of pages	12
Journal	Polymer Bulletin
Volume	67
Issue number	8
DOIs	https://doi.org/10.1007/s00289-011-0503-2
Publication status	Published - Nov 2011
Externally published	Yes

Keywords

Coating
Dendritic polyester
Epoxy resin
Maleate
Mechanical properties
Thermal properties

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10.1007/s00289-011-0503-2

Cite this

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title = "Synthesis and application on UV-curable epoxy/ dendritic maleate resin",

abstract = "The dendritic polyester, dendritic maleate, and epoxy/dendritic maleate resins were synthesized and analyzed by acid value, hydroxyl value, FT-IR, TGA, and DSC. The dendritic maleate and epoxy/dendritic maleate resins were applied in UV-curable coating, and the properties of the UV-curable coatings were compared. With the introduction of epoxy resin, the epoxy/dendritic maleate resin formed larger cross linked structure and more cavities which helped to improve the properties of coating. The epoxy/dendritic maleate resin exhibited higher thermal decomposition temperature and T g. The coating based on equal content of epoxy resin and dendritic maleate had higher gel content and better properties such as impact strength, adhesive strength, flexibility, pencil hardness, and solvent resistances. The SEM figures showed that the epoxy/dendritic maleate resin could form more cavities and improve the toughness of coating.",

keywords = "Coating, Dendritic polyester, Epoxy resin, Maleate, Mechanical properties, Thermal properties",

author = "Linya Zhang and Qingze Jiao and Yun Zhao and Mingji Zhou and Wei Feng and Yanrui Ge",

year = "2011",

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doi = "10.1007/s00289-011-0503-2",

language = "English",

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TY - JOUR

T1 - Synthesis and application on UV-curable epoxy/ dendritic maleate resin

AU - Zhang, Linya

AU - Jiao, Qingze

AU - Zhao, Yun

AU - Zhou, Mingji

AU - Feng, Wei

AU - Ge, Yanrui

PY - 2011/11

Y1 - 2011/11

N2 - The dendritic polyester, dendritic maleate, and epoxy/dendritic maleate resins were synthesized and analyzed by acid value, hydroxyl value, FT-IR, TGA, and DSC. The dendritic maleate and epoxy/dendritic maleate resins were applied in UV-curable coating, and the properties of the UV-curable coatings were compared. With the introduction of epoxy resin, the epoxy/dendritic maleate resin formed larger cross linked structure and more cavities which helped to improve the properties of coating. The epoxy/dendritic maleate resin exhibited higher thermal decomposition temperature and T g. The coating based on equal content of epoxy resin and dendritic maleate had higher gel content and better properties such as impact strength, adhesive strength, flexibility, pencil hardness, and solvent resistances. The SEM figures showed that the epoxy/dendritic maleate resin could form more cavities and improve the toughness of coating.

AB - The dendritic polyester, dendritic maleate, and epoxy/dendritic maleate resins were synthesized and analyzed by acid value, hydroxyl value, FT-IR, TGA, and DSC. The dendritic maleate and epoxy/dendritic maleate resins were applied in UV-curable coating, and the properties of the UV-curable coatings were compared. With the introduction of epoxy resin, the epoxy/dendritic maleate resin formed larger cross linked structure and more cavities which helped to improve the properties of coating. The epoxy/dendritic maleate resin exhibited higher thermal decomposition temperature and T g. The coating based on equal content of epoxy resin and dendritic maleate had higher gel content and better properties such as impact strength, adhesive strength, flexibility, pencil hardness, and solvent resistances. The SEM figures showed that the epoxy/dendritic maleate resin could form more cavities and improve the toughness of coating.

KW - Coating

KW - Dendritic polyester

KW - Epoxy resin

KW - Maleate

KW - Mechanical properties

KW - Thermal properties

UR - https://www.scopus.com/pages/publications/84855659879

U2 - 10.1007/s00289-011-0503-2

DO - 10.1007/s00289-011-0503-2

M3 - Article

AN - SCOPUS:84855659879

SN - 0170-0839

VL - 67

SP - 1583

EP - 1594

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 8

ER -

Synthesis and application on UV-curable epoxy/ dendritic maleate resin

Abstract

Keywords

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