Synthesis and application in solar cell of poly(3-octylthiophene)/cadmium sulfide nanocomposite

Zhiyue Han, Jingchang Zhang*, Xiuying Yang, Weiliang Cao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

A conducting polymer composite, poly(3-octylthiophene)/cadmium sulfide (POT/CdS) was first synthesized. Transmission electron microscope (TEM) and scanning electron microscope (SEM) depict the morphology of the samples, defining that CdS was successfully coated by poly(3-octylthiophene) molecules. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (IR) show that there is a chemical interaction in the composite. The energy gap of the POT/CdS composite is lower at 0.824 eV, which also shows that the optical performance of the new material is far superior to POT or CdS separately, by ultravioletvisible spectra (UVvis). Solar cell was sensitized by POT/CdS. A solar-to-electric energy conversion efficiency of 0.581% was attained with the system. The results show that POT/CdS nanocomposites are promising materials with excellent performance characteristics in photoelectric applications.

Original languageEnglish
Pages (from-to)483-490
Number of pages8
JournalSolar Energy Materials and Solar Cells
Volume95
Issue number2
DOIs
Publication statusPublished - Feb 2011
Externally publishedYes

Keywords

  • Chemical interaction
  • Composite material
  • Photoelectric performance
  • Solar cell

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