Syntheses and structures of lanthanide complexes with isonicotinate

Man Bo Zhang; Shou Tian Zheng; Guo Yu Yang

Syntheses and structures of lanthanide complexes with isonicotinate

Man Bo Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The crystal structures of two coordination polymers [Ln(IN) ₃(H₂O)₂]_n (Ln = Nd 1, Gd 2; IN = isonicotinate) were determined by single-crystal X-ray diffraction and further characterized by IR, elemental analysis and thermogravimetric analysis. Crystal data for 1: monoclinic, space group P2₁/c, a = 9.6636(5), b = 19.7532(10), c = 11.6183(6) Å, β = 112.032(1)°, V = 2055.83(18) Å³, Z = 4, D_c = 1.766 g/cm³, F(000) = 1076, μ = 2.575 mm^-1 and R = 0.0493; Crystal data for 2: monoclinic, space group C2/c, a = 20.251(2), b = 11.6199(11), c = 9.8240(9) Å, β = 115.505(3)°, V = 2086.4(3) Å³, Z = 4, D_c = 1.781 g/cm³, F(000) = 1092, μ = 3.228 mm ^-1 and R = 0.0695. In the title compounds, the center atoms Ln(III) are in a distorted square antiprismatic geometry and linked by bridging isonicotinate to form an infinite chain. The intermolecular hydrogen bonds lead to the formation of three-dimensional supramolecular structures.

Original language	English
Pages (from-to)	816-820
Number of pages	5
Journal	Jiegou Huaxue
Volume	24
Issue number	7
Publication status	Published - 2005
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Isonicotinate
Lanthanide

Cite this

@article{f2e2f6c3316f42b9b185071214facaf4,

title = "Syntheses and structures of lanthanide complexes with isonicotinate",

abstract = "The crystal structures of two coordination polymers [Ln(IN) 3(H2O)2]n (Ln = Nd 1, Gd 2; IN = isonicotinate) were determined by single-crystal X-ray diffraction and further characterized by IR, elemental analysis and thermogravimetric analysis. Crystal data for 1: monoclinic, space group P21/c, a = 9.6636(5), b = 19.7532(10), c = 11.6183(6) {\AA}, β = 112.032(1)°, V = 2055.83(18) {\AA}3, Z = 4, Dc = 1.766 g/cm3, F(000) = 1076, μ = 2.575 mm-1 and R = 0.0493; Crystal data for 2: monoclinic, space group C2/c, a = 20.251(2), b = 11.6199(11), c = 9.8240(9) {\AA}, β = 115.505(3)°, V = 2086.4(3) {\AA}3, Z = 4, Dc = 1.781 g/cm3, F(000) = 1092, μ = 3.228 mm -1 and R = 0.0695. In the title compounds, the center atoms Ln(III) are in a distorted square antiprismatic geometry and linked by bridging isonicotinate to form an infinite chain. The intermolecular hydrogen bonds lead to the formation of three-dimensional supramolecular structures.",

keywords = "Crystal structure, Hydrothermal synthesis, Isonicotinate, Lanthanide",

author = "Zhang, \{Man Bo\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2005",

language = "English",

volume = "24",

pages = "816--820",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "7",

}

TY - JOUR

T1 - Syntheses and structures of lanthanide complexes with isonicotinate

AU - Zhang, Man Bo

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - The crystal structures of two coordination polymers [Ln(IN) 3(H2O)2]n (Ln = Nd 1, Gd 2; IN = isonicotinate) were determined by single-crystal X-ray diffraction and further characterized by IR, elemental analysis and thermogravimetric analysis. Crystal data for 1: monoclinic, space group P21/c, a = 9.6636(5), b = 19.7532(10), c = 11.6183(6) Å, β = 112.032(1)°, V = 2055.83(18) Å3, Z = 4, Dc = 1.766 g/cm3, F(000) = 1076, μ = 2.575 mm-1 and R = 0.0493; Crystal data for 2: monoclinic, space group C2/c, a = 20.251(2), b = 11.6199(11), c = 9.8240(9) Å, β = 115.505(3)°, V = 2086.4(3) Å3, Z = 4, Dc = 1.781 g/cm3, F(000) = 1092, μ = 3.228 mm -1 and R = 0.0695. In the title compounds, the center atoms Ln(III) are in a distorted square antiprismatic geometry and linked by bridging isonicotinate to form an infinite chain. The intermolecular hydrogen bonds lead to the formation of three-dimensional supramolecular structures.

AB - The crystal structures of two coordination polymers [Ln(IN) 3(H2O)2]n (Ln = Nd 1, Gd 2; IN = isonicotinate) were determined by single-crystal X-ray diffraction and further characterized by IR, elemental analysis and thermogravimetric analysis. Crystal data for 1: monoclinic, space group P21/c, a = 9.6636(5), b = 19.7532(10), c = 11.6183(6) Å, β = 112.032(1)°, V = 2055.83(18) Å3, Z = 4, Dc = 1.766 g/cm3, F(000) = 1076, μ = 2.575 mm-1 and R = 0.0493; Crystal data for 2: monoclinic, space group C2/c, a = 20.251(2), b = 11.6199(11), c = 9.8240(9) Å, β = 115.505(3)°, V = 2086.4(3) Å3, Z = 4, Dc = 1.781 g/cm3, F(000) = 1092, μ = 3.228 mm -1 and R = 0.0695. In the title compounds, the center atoms Ln(III) are in a distorted square antiprismatic geometry and linked by bridging isonicotinate to form an infinite chain. The intermolecular hydrogen bonds lead to the formation of three-dimensional supramolecular structures.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Isonicotinate

KW - Lanthanide

UR - https://www.scopus.com/pages/publications/23044467799

M3 - Article

AN - SCOPUS:23044467799

SN - 0254-5861

VL - 24

SP - 816

EP - 820

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 7

ER -

Syntheses and structures of lanthanide complexes with isonicotinate

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