Syntheses and characterizations of hyperbranched polyphenylenes

Han Peng; Hong Chen Dong; Yu Ping Dong; De Min Jia; Ben Zhong Tang

Syntheses and characterizations of hyperbranched polyphenylenes

Han Peng
, Hong Chen Dong
, Yu Ping Dong
, De Min Jia
, Ben Zhong Tang^*

^*Corresponding author for this work

South China University of Technology
Hong Kong University of Science and Technology

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

New hyperbranched polyphenylenes with high molecular weights are synthesized by the copolycyclotrimerizations of 1,4-diethynylbenzene (I) with phenylacetylene (A), 1-octyne (B), and 1-dodecyne (C) catalyzed by TaCl ₅-Ph₄Sn. The polymers are completely soluble in common solvents such as toluene, THF, chloroform, and dichloromethane. The polymers are characterized by spectroscopic methods and all of the polymers give satisfactory analysis data corresponding to their expected molecular structures.

Original language	English
Pages (from-to)	501-503
Number of pages	3
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	22
Issue number	6
Publication status	Published - Dec 2004
Externally published	Yes

Keywords

Alkyne polycyclotrimerization
Hyperbranched polymers
Polyphenylenes

Cite this

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title = "Syntheses and characterizations of hyperbranched polyphenylenes",

abstract = "New hyperbranched polyphenylenes with high molecular weights are synthesized by the copolycyclotrimerizations of 1,4-diethynylbenzene (I) with phenylacetylene (A), 1-octyne (B), and 1-dodecyne (C) catalyzed by TaCl 5-Ph4Sn. The polymers are completely soluble in common solvents such as toluene, THF, chloroform, and dichloromethane. The polymers are characterized by spectroscopic methods and all of the polymers give satisfactory analysis data corresponding to their expected molecular structures.",

keywords = "Alkyne polycyclotrimerization, Hyperbranched polymers, Polyphenylenes",

author = "Han Peng and Dong, \{Hong Chen\} and Dong, \{Yu Ping\} and Jia, \{De Min\} and Tang, \{Ben Zhong\}",

year = "2004",

month = dec,

language = "English",

volume = "22",

pages = "501--503",

journal = "Chinese Journal of Polymer Science (English Edition)",

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T1 - Syntheses and characterizations of hyperbranched polyphenylenes

AU - Peng, Han

AU - Dong, Hong Chen

AU - Dong, Yu Ping

AU - Jia, De Min

AU - Tang, Ben Zhong

PY - 2004/12

Y1 - 2004/12

N2 - New hyperbranched polyphenylenes with high molecular weights are synthesized by the copolycyclotrimerizations of 1,4-diethynylbenzene (I) with phenylacetylene (A), 1-octyne (B), and 1-dodecyne (C) catalyzed by TaCl 5-Ph4Sn. The polymers are completely soluble in common solvents such as toluene, THF, chloroform, and dichloromethane. The polymers are characterized by spectroscopic methods and all of the polymers give satisfactory analysis data corresponding to their expected molecular structures.

AB - New hyperbranched polyphenylenes with high molecular weights are synthesized by the copolycyclotrimerizations of 1,4-diethynylbenzene (I) with phenylacetylene (A), 1-octyne (B), and 1-dodecyne (C) catalyzed by TaCl 5-Ph4Sn. The polymers are completely soluble in common solvents such as toluene, THF, chloroform, and dichloromethane. The polymers are characterized by spectroscopic methods and all of the polymers give satisfactory analysis data corresponding to their expected molecular structures.

KW - Alkyne polycyclotrimerization

KW - Hyperbranched polymers

KW - Polyphenylenes

UR - https://www.scopus.com/pages/publications/33644561089

M3 - Article

AN - SCOPUS:33644561089

SN - 0256-7679

VL - 22

SP - 501

EP - 503

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 6

ER -

Syntheses and characterizations of hyperbranched polyphenylenes

Abstract

Keywords

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