Syntheses and characterization of two new open-framework zinc phosphites with 12-ring channels, [H3N(CH2)4NH 3]·[Zn3(HPO3)4]·H 2O and [C3N2H5]2· [Zn3(HPO3)4]

Jian Xin Pan; Shou Tian Zheng; Guo Yu Yang

doi:10.1021/cg049878i

Syntheses and characterization of two new open-framework zinc phosphites with 12-ring channels, [H₃N(CH₂)₄NH ₃]·[Zn₃(HPO₃)₄]·H ₂O and [C₃N₂H₅]₂· [Zn₃(HPO₃)₄]

Jian Xin Pan
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Two new organically templated zinc phosphites, [H₃N(CH ₂)₄NH₃]·[Zn₃(HPO ₃)₄]·H₂O (1) and [C₃N ₂H₅]₂· [Zn₃(HPO ₃)₄] (2) have been synthesized under mild hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, inductively coupled plasma (ICP) analysis, powder X-ray diffraction, and thermogravimetric analysis. In addition to the same anionic framework compositions of [Zn ₃(HPO₃)₄]^2-, both phases consist of strictly alternating ZnO₄ tetrahedra and HPO₃ pseudo-pyramids linked through their vertexes to generate the three-dimensional frameworks with intersecting 8- and 12-membered ring channels, where the template molecules reside. Compound 1 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 7.7703(4) Å; b = 9.1499(4) Å; c = 14.4685(3) Å; α = 89.965(2)°; β = 87.050(2)°; γ = 65.332(2)°; V = 933.31(7) Å³; Z = 2. Compound 2 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 9.0238(4) Å; b = 9.0392(4) Å; c = 13.8071(6) Å; α = 95.965(2)°; β = 96.049-(2)°; γ = 110.228(2)°; V = 1038.92 (8) Å³; Z = 2.

Original language	English
Pages (from-to)	237-242
Number of pages	6
Journal	Crystal Growth and Design
Volume	5
Issue number	1
DOIs	https://doi.org/10.1021/cg049878i
Publication status	Published - Jan 2005
Externally published	Yes

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@article{4f5c0e56a85a4950aafe3256d8ffc443,

title = "Syntheses and characterization of two new open-framework zinc phosphites with 12-ring channels, [H3N(CH2)4NH 3]·[Zn3(HPO3)4]·H 2O and [C3N2H5]2· [Zn3(HPO3)4]",

abstract = "Two new organically templated zinc phosphites, [H3N(CH 2)4NH3]·[Zn3(HPO 3)4]·H2O (1) and [C3N 2H5]2· [Zn3(HPO 3)4] (2) have been synthesized under mild hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, inductively coupled plasma (ICP) analysis, powder X-ray diffraction, and thermogravimetric analysis. In addition to the same anionic framework compositions of [Zn 3(HPO3)4]2-, both phases consist of strictly alternating ZnO4 tetrahedra and HPO3 pseudo-pyramids linked through their vertexes to generate the three-dimensional frameworks with intersecting 8- and 12-membered ring channels, where the template molecules reside. Compound 1 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 7.7703(4) {\AA}; b = 9.1499(4) {\AA}; c = 14.4685(3) {\AA}; α = 89.965(2)°; β = 87.050(2)°; γ = 65.332(2)°; V = 933.31(7) {\AA}3; Z = 2. Compound 2 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 9.0238(4) {\AA}; b = 9.0392(4) {\AA}; c = 13.8071(6) {\AA}; α = 95.965(2)°; β = 96.049-(2)°; γ = 110.228(2)°; V = 1038.92 (8) {\AA}3; Z = 2.",

author = "Pan, \{Jian Xin\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2005",

month = jan,

doi = "10.1021/cg049878i",

language = "English",

volume = "5",

pages = "237--242",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Syntheses and characterization of two new open-framework zinc phosphites with 12-ring channels, [H3N(CH2)4NH 3]·[Zn3(HPO3)4]·H 2O and [C3N2H5]2· [Zn3(HPO3)4]

AU - Pan, Jian Xin

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005/1

Y1 - 2005/1

N2 - Two new organically templated zinc phosphites, [H3N(CH 2)4NH3]·[Zn3(HPO 3)4]·H2O (1) and [C3N 2H5]2· [Zn3(HPO 3)4] (2) have been synthesized under mild hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, inductively coupled plasma (ICP) analysis, powder X-ray diffraction, and thermogravimetric analysis. In addition to the same anionic framework compositions of [Zn 3(HPO3)4]2-, both phases consist of strictly alternating ZnO4 tetrahedra and HPO3 pseudo-pyramids linked through their vertexes to generate the three-dimensional frameworks with intersecting 8- and 12-membered ring channels, where the template molecules reside. Compound 1 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 7.7703(4) Å; b = 9.1499(4) Å; c = 14.4685(3) Å; α = 89.965(2)°; β = 87.050(2)°; γ = 65.332(2)°; V = 933.31(7) Å3; Z = 2. Compound 2 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 9.0238(4) Å; b = 9.0392(4) Å; c = 13.8071(6) Å; α = 95.965(2)°; β = 96.049-(2)°; γ = 110.228(2)°; V = 1038.92 (8) Å3; Z = 2.

AB - Two new organically templated zinc phosphites, [H3N(CH 2)4NH3]·[Zn3(HPO 3)4]·H2O (1) and [C3N 2H5]2· [Zn3(HPO 3)4] (2) have been synthesized under mild hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, inductively coupled plasma (ICP) analysis, powder X-ray diffraction, and thermogravimetric analysis. In addition to the same anionic framework compositions of [Zn 3(HPO3)4]2-, both phases consist of strictly alternating ZnO4 tetrahedra and HPO3 pseudo-pyramids linked through their vertexes to generate the three-dimensional frameworks with intersecting 8- and 12-membered ring channels, where the template molecules reside. Compound 1 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 7.7703(4) Å; b = 9.1499(4) Å; c = 14.4685(3) Å; α = 89.965(2)°; β = 87.050(2)°; γ = 65.332(2)°; V = 933.31(7) Å3; Z = 2. Compound 2 crystallizes in the triclinic system, space group P1 with the following cell parameters: a = 9.0238(4) Å; b = 9.0392(4) Å; c = 13.8071(6) Å; α = 95.965(2)°; β = 96.049-(2)°; γ = 110.228(2)°; V = 1038.92 (8) Å3; Z = 2.

UR - https://www.scopus.com/pages/publications/12844256928

U2 - 10.1021/cg049878i

DO - 10.1021/cg049878i

M3 - Article

AN - SCOPUS:12844256928

SN - 1528-7483

VL - 5

SP - 237

EP - 242

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 1

ER -

Syntheses and characterization of two new open-framework zinc phosphites with 12-ring channels, [H₃N(CH₂)₄NH ₃]·[Zn₃(HPO₃)₄]·H ₂O and [C₃N₂H₅]₂· [Zn₃(HPO₃)₄]

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