Synergistic improvement of mechanical and piezoelectric properties of the flexible piezoelectric ceramic composite and its high-precision preparation

Flexible piezoelectric ceramic composites (FPCCs) hold promising applications in fields such as flexible sensing and energy harvesting. However, the previous methods are difficult to achieve high-precision preparation of the FPCCs with complex structures, as well as the synergistic enhancement of piezoelectric performance and flexibility. In this study, by configuring a flexible resin matrix and employing a surface functionalization treatment on the piezoelectric ceramic particles, the flexibility and piezoelectric performance of the FPCCs are synergistically improved. Moreover, the addition of a light absorber, TiO₂, significantly improves the 3D printing precision. The mechanical properties, piezoelectric performance, and printing precision of the FPCCs are analyzed. It is found that the printing error is less than 2 μm, the tensile fracture strength is 4.07 MPa, the elongation at break is 350 %, and the piezoelectric constant d₃₃ can reach 7.7 pC/N. In addition, the cyclic loading tests show that FPCCs with high-precision 3D complex microstructure have good recovery performance. This study not only enriches the formulation of FPCCs slurry for 3D printing, but also provides a research foundation for the multifunctional applications.