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Synergistic effects in mixed gas chromatographic stationary phases containing heptakis (2.3.6-tri-O-pentyl)-β-Cyclodextrin and AgNO3 or TINO3 in the separation of xylene isomers

  • L. M. Yuan
  • , R. N. Fu*
  • , S. H. Gui
  • , X. T. Xie
  • , R. J. Dai
  • , X. X. Chen
  • , Q. H. Xu
  • *Corresponding author for this work
  • Beijing Institute of Technology
  • Yunnan Normal University
  • Yunnan University

Research output: Contribution to journalArticlepeer-review

Abstract

The gas chromatographic separation of xylene isomers using special mixed stationary phases consisting of heptakis(2.3.6-tri-O-pentyl)-β-CD-AgNO3, heptakis (2.3.6-tri-O-pentyl)-β-CD-TINO3 or bentone-34-AgNO3 is investigated. The first two have positive synergistic effects for the separation of m, and p-xylene isomers, but negative synergistic effects for the m, and o-isomers. The separation effects depend on temperature, mixing ratio and how mixing is accomplished.

Original languageEnglish
Pages (from-to)291-294
Number of pages4
JournalChromatographia
Volume46
Issue number5-6
DOIs
Publication statusPublished - 1997

Keywords

  • AgNO
  • Bentone-34
  • Gas chromatography
  • Heptakis(2.3.6-tri-O-pentyl)-β-CD
  • Mixed stationary phases
  • Synergistic effect
  • TINO

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