Supramolecular porous ionic network based on triazinonide and imidazolium: A template-free synthesis of meso-/macroporous organic materials: Via a one-pot reaction-assembly procedure

Ze Huan Hei; Gan Lin Song; Chen Yu Zhao; Wenhao Fan; Mu Hua Huang

doi:10.1039/c6ra20590a

Supramolecular porous ionic network based on triazinonide and imidazolium: A template-free synthesis of meso-/macroporous organic materials: Via a one-pot reaction-assembly procedure

Ze Huan Hei
, Gan Lin Song
, Chen Yu Zhao
, Wenhao Fan
, Mu Hua Huang^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology
Beijing Center for Physical and Chemical Analysis

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state ¹³C CP/TOSS NMR, elemental analysis and XPS. SPIN-1 shows a BET surface area up to 263 m² g^-1 (average pore size 11 nm), and a CO₂ capture capacity of 24.7 cm³ g^-1, which is competitive for Carbon Capture and Storage (CCS).

Original language	English
Pages (from-to)	92443-92448
Number of pages	6
Journal	RSC Advances
Volume	6
Issue number	95
DOIs	https://doi.org/10.1039/c6ra20590a
Publication status	Published - 2016

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title = "Supramolecular porous ionic network based on triazinonide and imidazolium: A template-free synthesis of meso-/macroporous organic materials: Via a one-pot reaction-assembly procedure",

abstract = "A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state 13C CP/TOSS NMR, elemental analysis and XPS. SPIN-1 shows a BET surface area up to 263 m2 g-1 (average pore size 11 nm), and a CO2 capture capacity of 24.7 cm3 g-1, which is competitive for Carbon Capture and Storage (CCS).",

author = "Hei, \{Ze Huan\} and Song, \{Gan Lin\} and Zhao, \{Chen Yu\} and Wenhao Fan and Huang, \{Mu Hua\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ra20590a",

language = "English",

volume = "6",

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journal = "RSC Advances",

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T1 - Supramolecular porous ionic network based on triazinonide and imidazolium

T2 - A template-free synthesis of meso-/macroporous organic materials: Via a one-pot reaction-assembly procedure

AU - Hei, Ze Huan

AU - Song, Gan Lin

AU - Zhao, Chen Yu

AU - Fan, Wenhao

AU - Huang, Mu Hua

PY - 2016

Y1 - 2016

N2 - A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state 13C CP/TOSS NMR, elemental analysis and XPS. SPIN-1 shows a BET surface area up to 263 m2 g-1 (average pore size 11 nm), and a CO2 capture capacity of 24.7 cm3 g-1, which is competitive for Carbon Capture and Storage (CCS).

AB - A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state 13C CP/TOSS NMR, elemental analysis and XPS. SPIN-1 shows a BET surface area up to 263 m2 g-1 (average pore size 11 nm), and a CO2 capture capacity of 24.7 cm3 g-1, which is competitive for Carbon Capture and Storage (CCS).

UR - https://www.scopus.com/pages/publications/84989277363

U2 - 10.1039/c6ra20590a

DO - 10.1039/c6ra20590a

M3 - Article

AN - SCOPUS:84989277363

SN - 2046-2069

VL - 6

SP - 92443

EP - 92448

JO - RSC Advances

JF - RSC Advances

IS - 95

ER -

Supramolecular porous ionic network based on triazinonide and imidazolium: A template-free synthesis of meso-/macroporous organic materials: Via a one-pot reaction-assembly procedure

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