Sulfonated polyimide membranes For polymer electrolyte fuel cells

K. Okamoto*, K. Matsuda, Z. Hu, K. Chen, N. Endo, M. Higa

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Citations (Scopus)

Abstract

Sulfonated polyimides (SPIs) bearing sulfophenoxy side groups were successfully prepared. Their uncross-linked and cross-linked membranes were evaluated as polymer electrolyte membranes for polymer electrolyte fuel cells (PEFCs). They maintained high mechanical strength and high proton conductivity after aging in water at 130 °C for 500 h, indicating their high water stability. PEFCs with the SPI membranes showed high performances at 90 °C and a high humidity (85 %RH) of supplied gases. They also showed fairly high performances even at a low humidity of 30%RH due to the back diffusion of water formed at the cathode. PEFCs with the cross-linked SPI membranes were operated under a constant current density of 0.5 A/cm2 at 90 °C and 85 %RH for 1600 h without any reduction in cell performance, indicating their high fuel cell durability. The SPI membranes have high potential for PEFCs at higher temperatures above 80 °C.

Original languageEnglish
Title of host publicationECS Transactions - Fuel Cell Seminar 2007
PublisherElectrochemical Society Inc.
Pages5-12
Number of pages8
Edition1
ISBN (Electronic)9781566776394
ISBN (Print)9781566776394
DOIs
Publication statusPublished - 2008
Externally publishedYes
EventFuel Cell Seminar 2007 - San Antonio, TX, United States
Duration: 15 Oct 200719 Oct 2007

Publication series

NameECS Transactions
Number1
Volume12
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

ConferenceFuel Cell Seminar 2007
Country/TerritoryUnited States
CitySan Antonio, TX
Period15/10/0719/10/07

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