Sulfonated polyimide hybrid membranes for polymer electrolyte fuel cell applications

Sulfonated Si-MCM-41 (SMCM) with an ion exchange capacity (IEC) of 2.3 mequiv. g^-1 was used as a hydrophilic and proton-conductive inorganic component. Sulfonated polyimide (SPI) based on 1,4,5,8-naphthalene tetracarboxylic dianhydride and 2,2′-bis(3-sulfophenoxy) benzidine was used as a host membrane component. The SMCM/SPI hybrid membrane (H1) with 20 wt% loading of SMCM and an IEC of 1.90 mequiv. g^-1 showed the high mechanical tensile strength and the slightly higher water vapor sorption than the host SPI membrane (M1) with an IEC of 1.86 mequiv. g^-1. H1 and M1 showed anisotropic membrane swelling with about 10 times larger swelling in thickness direction than in plane one. The proton conductivity at 60 °C of H1 was lower in water than that of M1, but comparable at 30% RH. At 90 °C, H1 showed the rather lower performance of polymer electrolyte fuel cell (PEFC) at 82% RH than M1 and fairly better performance at 30% RH. On the other hand, at 110 °C and low humidity less than 50% RH, H1 showed the much better PEFC performance than M1 and Nafion 112. This was due to the promoted back diffusion of produced water by the superior water-holding capacity of SMCM. The SMCM/SPI hybrid membranes have high potential for PEFCs at higher temperatures and lower humidities.