Study on TPP and DMMP as flame-retardant cosolvent in electrolytes for li-ion batteries

Qi Zhen Zhu; Ting Ting Jing; Nan Chen; Shu Guang Liu; Yi Jin; Ren Jie Chen; Feng Wu

doi:10.15918/j.tbit1001-0645.2015.10.020

Study on TPP and DMMP as flame-retardant cosolvent in electrolytes for li-ion batteries

Qi Zhen Zhu
, Ting Ting Jing
, Nan Chen
, Shu Guang Liu
, Yi Jin
, Ren Jie Chen^*
, Feng Wu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

To improve the safety of Li-ion battery, the specific flame-retardant electrolytes and their properties were studied. Triphenyl phosphate(TPP) and dimethyl methyl phosphonate (DMMP) were used as the cosolvent in 1M LiPF6/EC:DEC (1:1 in weight) to reformulate the nonflammable electrolyte. The flame-retarded ability, thermal and electrochemical performances with these electrolytes were studied. The results show that the optimal mass fractions are 55% TPP and 35% DMMP by controlling the flame-retardant efficiency (η≥0.9) of the electrolytes. Furthermore, the modified electrolyte matches the electrode materials well in both physical and electrochemical stability.

Original language	English
Pages (from-to)	1096-1100
Number of pages	5
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	35
Issue number	10
DOIs	https://doi.org/10.15918/j.tbit1001-0645.2015.10.020
Publication status	Published - 1 Oct 2015
Externally published	Yes

Keywords

DMMP
Flame-retardant electrolyte
Li-ion battery
TPP

Access to Document

10.15918/j.tbit1001-0645.2015.10.020

Cite this

@article{04d9d0e6afba4770bd7c3ab0092ab15a,

title = "Study on TPP and DMMP as flame-retardant cosolvent in electrolytes for li-ion batteries",

abstract = "To improve the safety of Li-ion battery, the specific flame-retardant electrolytes and their properties were studied. Triphenyl phosphate(TPP) and dimethyl methyl phosphonate (DMMP) were used as the cosolvent in 1M LiPF6/EC:DEC (1:1 in weight) to reformulate the nonflammable electrolyte. The flame-retarded ability, thermal and electrochemical performances with these electrolytes were studied. The results show that the optimal mass fractions are 55\% TPP and 35\% DMMP by controlling the flame-retardant efficiency (η≥0.9) of the electrolytes. Furthermore, the modified electrolyte matches the electrode materials well in both physical and electrochemical stability.",

keywords = "DMMP, Flame-retardant electrolyte, Li-ion battery, TPP",

author = "Zhu, \{Qi Zhen\} and Jing, \{Ting Ting\} and Nan Chen and Liu, \{Shu Guang\} and Yi Jin and Chen, \{Ren Jie\} and Feng Wu",

year = "2015",

month = oct,

day = "1",

doi = "10.15918/j.tbit1001-0645.2015.10.020",

language = "English",

volume = "35",

pages = "1096--1100",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "10",

}

TY - JOUR

T1 - Study on TPP and DMMP as flame-retardant cosolvent in electrolytes for li-ion batteries

AU - Zhu, Qi Zhen

AU - Jing, Ting Ting

AU - Chen, Nan

AU - Liu, Shu Guang

AU - Jin, Yi

AU - Chen, Ren Jie

AU - Wu, Feng

PY - 2015/10/1

Y1 - 2015/10/1

N2 - To improve the safety of Li-ion battery, the specific flame-retardant electrolytes and their properties were studied. Triphenyl phosphate(TPP) and dimethyl methyl phosphonate (DMMP) were used as the cosolvent in 1M LiPF6/EC:DEC (1:1 in weight) to reformulate the nonflammable electrolyte. The flame-retarded ability, thermal and electrochemical performances with these electrolytes were studied. The results show that the optimal mass fractions are 55% TPP and 35% DMMP by controlling the flame-retardant efficiency (η≥0.9) of the electrolytes. Furthermore, the modified electrolyte matches the electrode materials well in both physical and electrochemical stability.

AB - To improve the safety of Li-ion battery, the specific flame-retardant electrolytes and their properties were studied. Triphenyl phosphate(TPP) and dimethyl methyl phosphonate (DMMP) were used as the cosolvent in 1M LiPF6/EC:DEC (1:1 in weight) to reformulate the nonflammable electrolyte. The flame-retarded ability, thermal and electrochemical performances with these electrolytes were studied. The results show that the optimal mass fractions are 55% TPP and 35% DMMP by controlling the flame-retardant efficiency (η≥0.9) of the electrolytes. Furthermore, the modified electrolyte matches the electrode materials well in both physical and electrochemical stability.

KW - DMMP

KW - Flame-retardant electrolyte

KW - Li-ion battery

KW - TPP

UR - https://www.scopus.com/pages/publications/84949975685

U2 - 10.15918/j.tbit1001-0645.2015.10.020

DO - 10.15918/j.tbit1001-0645.2015.10.020

M3 - Article

AN - SCOPUS:84949975685

SN - 1001-0645

VL - 35

SP - 1096

EP - 1100

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 10

ER -

Study on TPP and DMMP as flame-retardant cosolvent in electrolytes for li-ion batteries

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this