Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride

Ni Zhang; Xiaomeng Zhou; Hengdao Quan; Akira Sekiya

doi:10.1016/j.jfluchem.2015.07.025

Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride

Ni Zhang
, Xiaomeng Zhou
, Hengdao Quan^*
, Akira Sekiya

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Abstract We presented recently a synthesis of toluene-2,4-diisocyanate (TDI) as one of the nine examples to verify the feasibility of an industrial appealing two-step method for isocyanates synthesis via amines and carbonyl fluoride (COF₂). Because more investigation was considered to be necessary for future industrial application, the two-step synthesis processes of TDI were studied in detail herein. The total yield of TDI increased 5.6% under the optimized experimental conditions. The influence of the excess COF₂ left in the reaction system was studied carefully according to a one-pot method.

Original language	English
Article number	8626
Pages (from-to)	208-213
Number of pages	6
Journal	Journal of Fluorine Chemistry
Volume	178
DOIs	https://doi.org/10.1016/j.jfluchem.2015.07.025
Publication status	Published - 1 Oct 2015

Keywords

Amine
Carbonyl fluoride
Synthesis
Toluene diisocyanate

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10.1016/j.jfluchem.2015.07.025

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title = "Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride",

abstract = "Abstract We presented recently a synthesis of toluene-2,4-diisocyanate (TDI) as one of the nine examples to verify the feasibility of an industrial appealing two-step method for isocyanates synthesis via amines and carbonyl fluoride (COF2). Because more investigation was considered to be necessary for future industrial application, the two-step synthesis processes of TDI were studied in detail herein. The total yield of TDI increased 5.6\% under the optimized experimental conditions. The influence of the excess COF2 left in the reaction system was studied carefully according to a one-pot method.",

keywords = "Amine, Carbonyl fluoride, Synthesis, Toluene diisocyanate",

author = "Ni Zhang and Xiaomeng Zhou and Hengdao Quan and Akira Sekiya",

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year = "2015",

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doi = "10.1016/j.jfluchem.2015.07.025",

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T1 - Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride

AU - Zhang, Ni

AU - Zhou, Xiaomeng

AU - Quan, Hengdao

AU - Sekiya, Akira

PY - 2015/10/1

Y1 - 2015/10/1

N2 - Abstract We presented recently a synthesis of toluene-2,4-diisocyanate (TDI) as one of the nine examples to verify the feasibility of an industrial appealing two-step method for isocyanates synthesis via amines and carbonyl fluoride (COF2). Because more investigation was considered to be necessary for future industrial application, the two-step synthesis processes of TDI were studied in detail herein. The total yield of TDI increased 5.6% under the optimized experimental conditions. The influence of the excess COF2 left in the reaction system was studied carefully according to a one-pot method.

AB - Abstract We presented recently a synthesis of toluene-2,4-diisocyanate (TDI) as one of the nine examples to verify the feasibility of an industrial appealing two-step method for isocyanates synthesis via amines and carbonyl fluoride (COF2). Because more investigation was considered to be necessary for future industrial application, the two-step synthesis processes of TDI were studied in detail herein. The total yield of TDI increased 5.6% under the optimized experimental conditions. The influence of the excess COF2 left in the reaction system was studied carefully according to a one-pot method.

KW - Amine

KW - Carbonyl fluoride

KW - Synthesis

KW - Toluene diisocyanate

UR - https://www.scopus.com/pages/publications/84939128622

U2 - 10.1016/j.jfluchem.2015.07.025

DO - 10.1016/j.jfluchem.2015.07.025

M3 - Article

AN - SCOPUS:84939128622

SN - 0022-1139

VL - 178

SP - 208

EP - 213

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

M1 - 8626

ER -

Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride

Abstract

Keywords

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