Abstract
Epoxy resins suffer from inherent brittleness, limiting their reliability in impact-resistant structures. This study addresses the dispersion–performance trade-off in nano-alumina (Al2O3)/epoxy composites by fabricating specimens with 0–15 wt% filler loadings using an optimized ultrasonic-mechanical dispersion strategy. Quasi-static and dynamic tensile behaviors (600–1600 s−1) were evaluated using a universal tester and a split Hopkinson tensile bar (SHTB) system equipped with high-sensitivity semiconductor strain gauges. Results identify a critical agglomeration threshold at 3 wt%. The 1 wt% composite exhibited optimal quasi-static strength (44.76 ± 0.25 MPa), a 4.0% improvement over the neat epoxy (43.04 ± 0.33 MPa). While all composites showed positive strain-rate sensitivity, nano-Al2O3 incorporation generally reduced dynamic strength, except for the 5 wt% composite at intermediate rates. Notably, the 15 wt% composite recovered to 78.49 ± 0.48 MPa at 1600 s−1 due to high-rate energy dissipation mechanisms. Microstructural analysis revealed a transition from brittle cleavage to a hybrid fracture mode dominated by microvoids and localized plastic tearing. This work quantitatively defines the optimal loading window for nano-Al2O3/epoxy composites in protective engineering.
| Original language | English |
|---|---|
| Article number | 1861 |
| Journal | Polymers |
| Volume | 18 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Aug 2026 |
| Externally published | Yes |
Keywords
- dynamic tensile behavior
- fracture toughness
- interfacial adhesion
- nano-AlO/epoxy composites
- particle agglomeration
- quasi-static tensile behavior
- strain rate sensitivity
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