Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)3] n: Diffusion synthesis, crystal structure, and thermal analyses

Jinyu Guo; Tonglai Zhang; Jianguo Zhang; Yanhong Liu; Wei Yu; Ruifeng Wu

doi:10.1007/s11224-006-9075-4

Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)₃] _n: Diffusion synthesis, crystal structure, and thermal analyses

Jinyu Guo
, Tonglai Zhang^*
, Jianguo Zhang
, Yanhong Liu
, Wei Yu
, Ruifeng Wu

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The crystal of the coordination polymer [Cd(1,3,5-btc)(py)₃] _n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.

Original language	English
Pages (from-to)	577-583
Number of pages	7
Journal	Structural Chemistry
Volume	17
Issue number	6
DOIs	https://doi.org/10.1007/s11224-006-9075-4
Publication status	Published - Dec 2006

Keywords

1,3,5-benzenetricarboxylic acid
Chain coordination polymer
Crystal structure
Non-isothermal kinetics
Thermal decomposition mechanism

Access to Document

10.1007/s11224-006-9075-4

Cite this

@article{4e471133ff4b43ebb63de307afb35c9a,

title = "Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)3] n: Diffusion synthesis, crystal structure, and thermal analyses",

abstract = "The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.",

keywords = "1,3,5-benzenetricarboxylic acid, Chain coordination polymer, Crystal structure, Non-isothermal kinetics, Thermal decomposition mechanism",

author = "Jinyu Guo and Tonglai Zhang and Jianguo Zhang and Yanhong Liu and Wei Yu and Ruifeng Wu",

year = "2006",

month = dec,

doi = "10.1007/s11224-006-9075-4",

language = "English",

volume = "17",

pages = "577--583",

journal = "Structural Chemistry",

issn = "1040-0400",

publisher = "Springer",

number = "6",

}

TY - JOUR

T1 - Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)3] n

T2 - Diffusion synthesis, crystal structure, and thermal analyses

AU - Guo, Jinyu

AU - Zhang, Tonglai

AU - Zhang, Jianguo

AU - Liu, Yanhong

AU - Yu, Wei

AU - Wu, Ruifeng

PY - 2006/12

Y1 - 2006/12

N2 - The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.

AB - The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.

KW - 1,3,5-benzenetricarboxylic acid

KW - Chain coordination polymer

KW - Crystal structure

KW - Non-isothermal kinetics

KW - Thermal decomposition mechanism

UR - https://www.scopus.com/pages/publications/33845489437

U2 - 10.1007/s11224-006-9075-4

DO - 10.1007/s11224-006-9075-4

M3 - Article

AN - SCOPUS:33845489437

SN - 1040-0400

VL - 17

SP - 577

EP - 583

JO - Structural Chemistry

JF - Structural Chemistry

IS - 6

ER -

Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)₃] _n: Diffusion synthesis, crystal structure, and thermal analyses

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this