Study on carbon-coating Li3V2(PO4)3 cathode materials prepared with different carbon sources

Li Yuejiao; Hong Liang; Sun Jingqiu; Wu Feng

doi:10.4028/www.scientific.net/AMR.581-582.565

Study on carbon-coating Li₃V₂(PO₄)₃ cathode materials prepared with different carbon sources

Li Yuejiao^*
, Hong Liang
, Sun Jingqiu
, Wu Feng

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Citations (Scopus)

Abstract

Lithium-ion battery cathode materials, Li₃V₂(PO₄)₃/C, were prepared via rheological phase method. Li₂CO₃, NH₄H₂PO₄, V₂O₅ were employed as raw materials, and citric acid or polyethylene glycol (PEG) was used as the chelating agent (carbon source). The structure, morphology characters and the electrochemical performances of the samples were tested. The results show that modification by carbon-coating is favorable for the growth of particles. The primary particle size obviously decreases with PEG added, while the agglomeration of primary particles could be inhibited using the citric acid as carbon source, which makes particle size more uniform. Moreover, the electrochemical test results show that both the two kinds of carbon sources can effectively improve the specific capacity and the cycling performance compared with the uncoated sample.

Original language	English
Title of host publication	Frontiers of Materials, Chemical and Metallurgical Technologies
Pages	565-569
Number of pages	5
Edition	1
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.581-582.565
Publication status	Published - 2012
Event	2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012 - KunMing, China Duration: 12 Oct 2012 → 13 Oct 2012

Publication series

Name	Advanced Materials Research
Number	1
Volume	581-582
ISSN (Print)	1022-6680

Conference

Conference	2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012
Country/Territory	China
City	KunMing
Period	12/10/12 → 13/10/12

Keywords

Cathode material
Lithium vanadium phosphate
Power li-ion batteries
Rheological

Access to Document

10.4028/www.scientific.net/AMR.581-582.565

Cite this

@inproceedings{8a9e64eb833b4a2e8a3678a57181fdf7,

title = "Study on carbon-coating Li3V2(PO4)3 cathode materials prepared with different carbon sources",

abstract = "Lithium-ion battery cathode materials, Li3V2(PO4)3/C, were prepared via rheological phase method. Li2CO3, NH4H2PO4, V2O5 were employed as raw materials, and citric acid or polyethylene glycol (PEG) was used as the chelating agent (carbon source). The structure, morphology characters and the electrochemical performances of the samples were tested. The results show that modification by carbon-coating is favorable for the growth of particles. The primary particle size obviously decreases with PEG added, while the agglomeration of primary particles could be inhibited using the citric acid as carbon source, which makes particle size more uniform. Moreover, the electrochemical test results show that both the two kinds of carbon sources can effectively improve the specific capacity and the cycling performance compared with the uncoated sample.",

keywords = "Cathode material, Lithium vanadium phosphate, Power li-ion batteries, Rheological",

author = "Li Yuejiao and Hong Liang and Sun Jingqiu and Wu Feng",

year = "2012",

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language = "English",

isbn = "9783037855126",

series = "Advanced Materials Research",

number = "1",

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booktitle = "Frontiers of Materials, Chemical and Metallurgical Technologies",

edition = "1",

note = "2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012 ; Conference date: 12-10-2012 Through 13-10-2012",

}

Yuejiao, L, Liang, H, Jingqiu, S & Feng, W 2012, Study on carbon-coating Li₃V₂(PO₄)₃ cathode materials prepared with different carbon sources. in Frontiers of Materials, Chemical and Metallurgical Technologies. 1 edn, Advanced Materials Research, no. 1, vol. 581-582, pp. 565-569, 2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012, KunMing, China, 12/10/12. https://doi.org/10.4028/www.scientific.net/AMR.581-582.565

Study on carbon-coating Li₃V₂(PO₄)₃ cathode materials prepared with different carbon sources. / Yuejiao, Li; Liang, Hong; Jingqiu, Sun et al.
Frontiers of Materials, Chemical and Metallurgical Technologies. 1. ed. 2012. p. 565-569 (Advanced Materials Research; Vol. 581-582, No. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Yuejiao, Li

AU - Liang, Hong

AU - Jingqiu, Sun

AU - Feng, Wu

PY - 2012

Y1 - 2012

N2 - Lithium-ion battery cathode materials, Li3V2(PO4)3/C, were prepared via rheological phase method. Li2CO3, NH4H2PO4, V2O5 were employed as raw materials, and citric acid or polyethylene glycol (PEG) was used as the chelating agent (carbon source). The structure, morphology characters and the electrochemical performances of the samples were tested. The results show that modification by carbon-coating is favorable for the growth of particles. The primary particle size obviously decreases with PEG added, while the agglomeration of primary particles could be inhibited using the citric acid as carbon source, which makes particle size more uniform. Moreover, the electrochemical test results show that both the two kinds of carbon sources can effectively improve the specific capacity and the cycling performance compared with the uncoated sample.

AB - Lithium-ion battery cathode materials, Li3V2(PO4)3/C, were prepared via rheological phase method. Li2CO3, NH4H2PO4, V2O5 were employed as raw materials, and citric acid or polyethylene glycol (PEG) was used as the chelating agent (carbon source). The structure, morphology characters and the electrochemical performances of the samples were tested. The results show that modification by carbon-coating is favorable for the growth of particles. The primary particle size obviously decreases with PEG added, while the agglomeration of primary particles could be inhibited using the citric acid as carbon source, which makes particle size more uniform. Moreover, the electrochemical test results show that both the two kinds of carbon sources can effectively improve the specific capacity and the cycling performance compared with the uncoated sample.

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