Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs 2Mo 18O 62] n in aprotic media

Shu Yan Zhang; Hao Ran Sun; Guo Yu Yang; Ji Qing Xu

Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ⁿ in aprotic media

Shu Yan Zhang, Hao Ran Sun, Guo Yu Yang, Ji Qing Xu

Jilin University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The mixed-valence heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ⁿ (n = 6, 7, 8, 9) were investigated by electrochemical and in-situ UV-Vis-Near-IR and FTIR spectroelectrochemical methods in aprotic media. The results indicate that the heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ^5- with four step one electron transfer reductions and the mixed-valence heteropolyanions [HAs ₂Mo ₁₈O ₆₂] ⁿ (n = 6, 7, 8, 9) were formed after electroreduction. The mixed-valence heteropolyanions have IVCT bands in Near-IR spectral region. The characteristic absorption of Mo = O double bond and the Mo - O bridge bond shift to low wavenumber after electroreduction.

Original language	English
Pages (from-to)	x28-776
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	18
Issue number	5
Publication status	Published - 1997
Externally published	Yes

Keywords

Aprotic media
Electroreduction
In situ spectroelectrochemistry
Mixed-valence compound

Cite this

Zhang, Shu Yan ; Sun, Hao Ran ; Yang, Guo Yu et al. / Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ⁿ in aprotic media. In: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities. 1997 ; Vol. 18, No. 5. pp. x28-776.

@article{18ae148354824ef4996f0957880c0960,

title = "Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs 2Mo 18O 62] n in aprotic media",

abstract = "The mixed-valence heteropolyanion [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were investigated by electrochemical and in-situ UV-Vis-Near-IR and FTIR spectroelectrochemical methods in aprotic media. The results indicate that the heteropolyanion [HAs 2Mo 18O 62] 5- with four step one electron transfer reductions and the mixed-valence heteropolyanions [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were formed after electroreduction. The mixed-valence heteropolyanions have IVCT bands in Near-IR spectral region. The characteristic absorption of Mo = O double bond and the Mo - O bridge bond shift to low wavenumber after electroreduction.",

keywords = "Aprotic media, Electroreduction, In situ spectroelectrochemistry, Mixed-valence compound",

author = "Zhang, {Shu Yan} and Sun, {Hao Ran} and Yang, {Guo Yu} and Xu, {Ji Qing}",

year = "1997",

language = "English",

volume = "18",

pages = "x28--776",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "5",

}

Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ⁿ in aprotic media. / Zhang, Shu Yan; Sun, Hao Ran; Yang, Guo Yu et al.
In: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, Vol. 18, No. 5, 1997, p. x28-776.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs 2Mo 18O 62] n in aprotic media

AU - Zhang, Shu Yan

AU - Sun, Hao Ran

AU - Yang, Guo Yu

AU - Xu, Ji Qing

PY - 1997

Y1 - 1997

N2 - The mixed-valence heteropolyanion [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were investigated by electrochemical and in-situ UV-Vis-Near-IR and FTIR spectroelectrochemical methods in aprotic media. The results indicate that the heteropolyanion [HAs 2Mo 18O 62] 5- with four step one electron transfer reductions and the mixed-valence heteropolyanions [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were formed after electroreduction. The mixed-valence heteropolyanions have IVCT bands in Near-IR spectral region. The characteristic absorption of Mo = O double bond and the Mo - O bridge bond shift to low wavenumber after electroreduction.

AB - The mixed-valence heteropolyanion [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were investigated by electrochemical and in-situ UV-Vis-Near-IR and FTIR spectroelectrochemical methods in aprotic media. The results indicate that the heteropolyanion [HAs 2Mo 18O 62] 5- with four step one electron transfer reductions and the mixed-valence heteropolyanions [HAs 2Mo 18O 62] n (n = 6, 7, 8, 9) were formed after electroreduction. The mixed-valence heteropolyanions have IVCT bands in Near-IR spectral region. The characteristic absorption of Mo = O double bond and the Mo - O bridge bond shift to low wavenumber after electroreduction.

KW - Aprotic media

KW - Electroreduction

KW - In situ spectroelectrochemistry

KW - Mixed-valence compound

UR - http://www.scopus.com/inward/record.url?scp=2842617205&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2842617205

SN - 0251-0790

VL - 18

SP - x28-776

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 5

ER -

Studies on mixed-valence compounds ( II ) - Electrochemical and in situ UV-vis-near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs ₂Mo ₁₈O ₆₂] ⁿ in aprotic media

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