TY - JOUR
T1 - Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions
AU - Deng, Yuan
AU - Ding, Ting Zhen
AU - Li, Yong
PY - 2002
Y1 - 2002
N2 - A series of new complexes, [HB{pzAn}3]CuOAc (1), [HB{pzAn}3]CuCl(pzAnH) (2), ([HB{pzAn,Me}3]Cu)2OAc (3) and [HB{pzAn,Me}3]CuCl(pzAn,MeH) (4) [pzAn = 3-(p-anisyl)pyrazolyl, pzAn,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands vas(CO2) and vs(CO2) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).
AB - A series of new complexes, [HB{pzAn}3]CuOAc (1), [HB{pzAn}3]CuCl(pzAnH) (2), ([HB{pzAn,Me}3]Cu)2OAc (3) and [HB{pzAn,Me}3]CuCl(pzAn,MeH) (4) [pzAn = 3-(p-anisyl)pyrazolyl, pzAn,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands vas(CO2) and vs(CO2) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).
UR - http://www.scopus.com/inward/record.url?scp=0036392222&partnerID=8YFLogxK
U2 - 10.1081/SIM-120003204
DO - 10.1081/SIM-120003204
M3 - Article
AN - SCOPUS:0036392222
SN - 0094-5714
VL - 32
SP - 219
EP - 229
JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
IS - 2
ER -