Structure, thermodynamics and sensitivity property of (TAGH)CIO4

Shu Yuan Qi; Tong Lai Zhang; Guo Jun Ao; Jian Guo Zhang; Li Yang

Structure, thermodynamics and sensitivity property of (TAGH)CIO₄

Shu Yuan Qi^*, Tong Lai Zhang, Guo Jun Ao, Jian Guo Zhang, Li Yang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Triaminoguandine Perchlorate was synthesized with triaminoguandine and perchloric acid as primary materials. The crystal structure was determined by X-ray single crystal diffraction analysis. The results show that the title compound belongs to monoclinic system with P2(1)/c space group and cell parameters of a=1. 021 3(11) nm,b=1. 486 9(15)nm,c=l. 093 6(11)nm,β=102. 91(2)°. The title compound,with formula of CH₉ClN ₆O₄, is an ionic compound formed by [C(N₂H ₃)₃]⁺ and ClO₄^-. There are a lot of intramolecular and intermolecular hydrogen bonds, which make it stable. The title compound was characterized by elemental analysis, FTIR, DSC, TG-DTG. The results show that the title compound lost 99. 7% at 457. 03°C with a heating rate of 10°C/min. The sensitivity test results show that it has low friction sensitivity and has no frame sensitivity and impact sensitivity under the sensitivity test conditions.

Original language	English
Pages (from-to)	35-39
Number of pages	5
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	32
Issue number	6
Publication status	Published - 2009

Keywords

(tAGH)ClO
Crystal structure
Mechanical sensitivity
Physical chemistry
Thermal analysis
Triaminoguandine

Cite this

@article{8404470823ca4332b0f0d75157055868,

title = "Structure, thermodynamics and sensitivity property of (TAGH)CIO4",

abstract = "Triaminoguandine Perchlorate was synthesized with triaminoguandine and perchloric acid as primary materials. The crystal structure was determined by X-ray single crystal diffraction analysis. The results show that the title compound belongs to monoclinic system with P2(1)/c space group and cell parameters of a=1. 021 3(11) nm,b=1. 486 9(15)nm,c=l. 093 6(11)nm,β=102. 91(2)°. The title compound,with formula of CH9ClN 6O4, is an ionic compound formed by [C(N2H 3)3]+ and ClO4-. There are a lot of intramolecular and intermolecular hydrogen bonds, which make it stable. The title compound was characterized by elemental analysis, FTIR, DSC, TG-DTG. The results show that the title compound lost 99. 7\% at 457. 03°C with a heating rate of 10°C/min. The sensitivity test results show that it has low friction sensitivity and has no frame sensitivity and impact sensitivity under the sensitivity test conditions.",

keywords = "(tAGH)ClO, Crystal structure, Mechanical sensitivity, Physical chemistry, Thermal analysis, Triaminoguandine",

author = "Qi, \{Shu Yuan\} and Zhang, \{Tong Lai\} and Ao, \{Guo Jun\} and Zhang, \{Jian Guo\} and Li Yang",

year = "2009",

language = "English",

volume = "32",

pages = "35--39",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "6",

}

TY - JOUR

T1 - Structure, thermodynamics and sensitivity property of (TAGH)CIO4

AU - Qi, Shu Yuan

AU - Zhang, Tong Lai

AU - Ao, Guo Jun

AU - Zhang, Jian Guo

AU - Yang, Li

PY - 2009

Y1 - 2009

N2 - Triaminoguandine Perchlorate was synthesized with triaminoguandine and perchloric acid as primary materials. The crystal structure was determined by X-ray single crystal diffraction analysis. The results show that the title compound belongs to monoclinic system with P2(1)/c space group and cell parameters of a=1. 021 3(11) nm,b=1. 486 9(15)nm,c=l. 093 6(11)nm,β=102. 91(2)°. The title compound,with formula of CH9ClN 6O4, is an ionic compound formed by [C(N2H 3)3]+ and ClO4-. There are a lot of intramolecular and intermolecular hydrogen bonds, which make it stable. The title compound was characterized by elemental analysis, FTIR, DSC, TG-DTG. The results show that the title compound lost 99. 7% at 457. 03°C with a heating rate of 10°C/min. The sensitivity test results show that it has low friction sensitivity and has no frame sensitivity and impact sensitivity under the sensitivity test conditions.

AB - Triaminoguandine Perchlorate was synthesized with triaminoguandine and perchloric acid as primary materials. The crystal structure was determined by X-ray single crystal diffraction analysis. The results show that the title compound belongs to monoclinic system with P2(1)/c space group and cell parameters of a=1. 021 3(11) nm,b=1. 486 9(15)nm,c=l. 093 6(11)nm,β=102. 91(2)°. The title compound,with formula of CH9ClN 6O4, is an ionic compound formed by [C(N2H 3)3]+ and ClO4-. There are a lot of intramolecular and intermolecular hydrogen bonds, which make it stable. The title compound was characterized by elemental analysis, FTIR, DSC, TG-DTG. The results show that the title compound lost 99. 7% at 457. 03°C with a heating rate of 10°C/min. The sensitivity test results show that it has low friction sensitivity and has no frame sensitivity and impact sensitivity under the sensitivity test conditions.

KW - (tAGH)ClO

KW - Crystal structure

KW - Mechanical sensitivity

KW - Physical chemistry

KW - Thermal analysis

KW - Triaminoguandine

UR - https://www.scopus.com/pages/publications/77950191681

M3 - Article

AN - SCOPUS:77950191681

SN - 1007-7812

VL - 32

SP - 35

EP - 39

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 6

ER -

Structure, thermodynamics and sensitivity property of (TAGH)CIO₄

Abstract

Keywords

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