Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs–C72

Yongqiang Feng; Taishan Wang; Jingyi Wu; Lai Feng; Junfeng Xiang; Yihan Ma; Zhuxia Zhang; Li Jiang; Chunying Shu; Chunru Wang

doi:10.1039/c3nr01739g

Structural and electronic studies of metal carbide clusterfullerene Sc₂C₂@C_s–C₇₂

Yongqiang Feng
, Taishan Wang^*
, Jingyi Wu
, Lai Feng
, Junfeng Xiang
, Yihan Ma
, Zhuxia Zhang
, Li Jiang
, Chunying Shu
, Chunru Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

We present a metal carbide clusterfullerene Sc₂C₂@C_s(10528)–C₇₂, whose structure has been baffling for many years. A motional endohedral Sc₂C₂ cluster, special molecule geometry and electronic structure were found in Sc₂C₂@C_s(10528)–C₇₂. The paramagnetic Sc₂C₂@C_s–C₇₂ anion radical was successfully prepared by a chemical reduction method and hyperfine couplings in the ESR spectrum were observed.

Original language	English
Pages (from-to)	6704-6707
Number of pages	4
Journal	Nanoscale
Volume	5
Issue number	15
DOIs	https://doi.org/10.1039/c3nr01739g
Publication status	Published - 11 Jul 2013
Externally published	Yes

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title = "Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs–C72",

abstract = "We present a metal carbide clusterfullerene Sc2C2@Cs(10528)–C72, whose structure has been baffling for many years. A motional endohedral Sc2C2 cluster, special molecule geometry and electronic structure were found in Sc2C2@Cs(10528)–C72. The paramagnetic Sc2C2@Cs–C72 anion radical was successfully prepared by a chemical reduction method and hyperfine couplings in the ESR spectrum were observed.",

author = "Yongqiang Feng and Taishan Wang and Jingyi Wu and Lai Feng and Junfeng Xiang and Yihan Ma and Zhuxia Zhang and Li Jiang and Chunying Shu and Chunru Wang",

year = "2013",

month = jul,

day = "11",

doi = "10.1039/c3nr01739g",

language = "English",

volume = "5",

pages = "6704--6707",

journal = "Nanoscale",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs–C72

AU - Feng, Yongqiang

AU - Wang, Taishan

AU - Wu, Jingyi

AU - Feng, Lai

AU - Xiang, Junfeng

AU - Ma, Yihan

AU - Zhang, Zhuxia

AU - Jiang, Li

AU - Shu, Chunying

AU - Wang, Chunru

PY - 2013/7/11

Y1 - 2013/7/11

N2 - We present a metal carbide clusterfullerene Sc2C2@Cs(10528)–C72, whose structure has been baffling for many years. A motional endohedral Sc2C2 cluster, special molecule geometry and electronic structure were found in Sc2C2@Cs(10528)–C72. The paramagnetic Sc2C2@Cs–C72 anion radical was successfully prepared by a chemical reduction method and hyperfine couplings in the ESR spectrum were observed.

AB - We present a metal carbide clusterfullerene Sc2C2@Cs(10528)–C72, whose structure has been baffling for many years. A motional endohedral Sc2C2 cluster, special molecule geometry and electronic structure were found in Sc2C2@Cs(10528)–C72. The paramagnetic Sc2C2@Cs–C72 anion radical was successfully prepared by a chemical reduction method and hyperfine couplings in the ESR spectrum were observed.

UR - https://www.scopus.com/pages/publications/84889607655

U2 - 10.1039/c3nr01739g

DO - 10.1039/c3nr01739g

M3 - Article

AN - SCOPUS:84889607655

SN - 2040-3364

VL - 5

SP - 6704

EP - 6707

JO - Nanoscale

JF - Nanoscale

IS - 15

ER -

Structural and electronic studies of metal carbide clusterfullerene Sc₂C₂@C_s–C₇₂

Abstract

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