Stoichiometric self-assembly of shape-persistent 2D complexes: A facile route to a symmetric supramacromolecular spoked wheel

Jin Liang Wang; Xiaopeng Li; Xiaocun Lu; I. Fan Hsieh; Yan Cao; Charles N. Moorefield; Chrys Wesdemiotis; Stephen Z.D. Cheng; George R. Newkome

doi:10.1021/ja203645m

Stoichiometric self-assembly of shape-persistent 2D complexes: A facile route to a symmetric supramacromolecular spoked wheel

Jin Liang Wang, Xiaopeng Li, Xiaocun Lu, I. Fan Hsieh, Yan Cao, Charles N. Moorefield, Chrys Wesdemiotis^*, Stephen Z.D. Cheng, George R. Newkome

^*Corresponding author for this work

University of Akron

Research output: Contribution to journal › Article › peer-review

140 Citations (Scopus)

Abstract

An approach to multicomponent coordination-driven self-assembly of the first terpyridine-based, shape-persistent, giant two-dimensional D _6h supramacromolecular spoked wheel is reported. Mixing core T6, rim T3, and Zn ^II or Cd ^II ions in a stoichiometric ratio (1:6:12) permitted the selective generation of a highly symmetric spoked wheel in 94% isolated yield via geometric and thermodynamic control. The products were characterized by a combination of traveling-wave ion mobility mass spectrometry and NMR techniques together with TEM imaging, which agreed with computational simulations.

Original language	English
Pages (from-to)	11450-11453
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	30
DOIs	https://doi.org/10.1021/ja203645m
Publication status	Published - 3 Aug 2011
Externally published	Yes

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title = "Stoichiometric self-assembly of shape-persistent 2D complexes: A facile route to a symmetric supramacromolecular spoked wheel",

abstract = "An approach to multicomponent coordination-driven self-assembly of the first terpyridine-based, shape-persistent, giant two-dimensional D 6h supramacromolecular spoked wheel is reported. Mixing core T6, rim T3, and Zn II or Cd II ions in a stoichiometric ratio (1:6:12) permitted the selective generation of a highly symmetric spoked wheel in 94% isolated yield via geometric and thermodynamic control. The products were characterized by a combination of traveling-wave ion mobility mass spectrometry and NMR techniques together with TEM imaging, which agreed with computational simulations.",

author = "Wang, {Jin Liang} and Xiaopeng Li and Xiaocun Lu and Hsieh, {I. Fan} and Yan Cao and Moorefield, {Charles N.} and Chrys Wesdemiotis and Cheng, {Stephen Z.D.} and Newkome, {George R.}",

year = "2011",

month = aug,

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doi = "10.1021/ja203645m",

language = "English",

volume = "133",

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T2 - A facile route to a symmetric supramacromolecular spoked wheel

AU - Wang, Jin Liang

AU - Li, Xiaopeng

AU - Lu, Xiaocun

AU - Hsieh, I. Fan

AU - Cao, Yan

AU - Moorefield, Charles N.

AU - Wesdemiotis, Chrys

AU - Cheng, Stephen Z.D.

AU - Newkome, George R.

PY - 2011/8/3

Y1 - 2011/8/3

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AB - An approach to multicomponent coordination-driven self-assembly of the first terpyridine-based, shape-persistent, giant two-dimensional D 6h supramacromolecular spoked wheel is reported. Mixing core T6, rim T3, and Zn II or Cd II ions in a stoichiometric ratio (1:6:12) permitted the selective generation of a highly symmetric spoked wheel in 94% isolated yield via geometric and thermodynamic control. The products were characterized by a combination of traveling-wave ion mobility mass spectrometry and NMR techniques together with TEM imaging, which agreed with computational simulations.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 30

ER -

Stoichiometric self-assembly of shape-persistent 2D complexes: A facile route to a symmetric supramacromolecular spoked wheel

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