Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

Ying Guo; Xiu Long Yang; Rong Jia Wei; Lan Sun Zheng; Jun Tao

doi:10.1021/acs.inorgchem.5b01344

Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

Ying Guo
, Xiu Long Yang
, Rong Jia Wei
, Lan Sun Zheng
, Jun Tao^*

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

A mononuclear compound, [Co^II(pyterpy)₂](PF₆)₂·2CH₃OH [2; pyterpy = 4′-(4⌄-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [Co^II(pyterpy)₂](PF₆)₂·2CH₂Cl₂·CH₃OH (3).

Original language	English
Pages (from-to)	7670-7672
Number of pages	3
Journal	Inorganic Chemistry
Volume	54
Issue number	16
DOIs	https://doi.org/10.1021/acs.inorgchem.5b01344
Publication status	Published - 17 Aug 2015
Externally published	Yes

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10.1021/acs.inorgchem.5b01344

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title = "Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex",

abstract = "A mononuclear compound, [CoII(pyterpy)2](PF6)2·2CH3OH [2; pyterpy = 4′-(4⌄-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2](PF6)2·2CH2Cl2·CH3OH (3).",

author = "Ying Guo and Yang, \{Xiu Long\} and Wei, \{Rong Jia\} and Zheng, \{Lan Sun\} and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = aug,

day = "17",

doi = "10.1021/acs.inorgchem.5b01344",

language = "English",

volume = "54",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

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TY - JOUR

T1 - Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

AU - Guo, Ying

AU - Yang, Xiu Long

AU - Wei, Rong Jia

AU - Zheng, Lan Sun

AU - Tao, Jun

PY - 2015/8/17

Y1 - 2015/8/17

N2 - A mononuclear compound, [CoII(pyterpy)2](PF6)2·2CH3OH [2; pyterpy = 4′-(4⌄-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2](PF6)2·2CH2Cl2·CH3OH (3).

AB - A mononuclear compound, [CoII(pyterpy)2](PF6)2·2CH3OH [2; pyterpy = 4′-(4⌄-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2](PF6)2·2CH2Cl2·CH3OH (3).

UR - https://www.scopus.com/pages/publications/84939420088

U2 - 10.1021/acs.inorgchem.5b01344

DO - 10.1021/acs.inorgchem.5b01344

M3 - Article

AN - SCOPUS:84939420088

SN - 0020-1669

VL - 54

SP - 7670

EP - 7672

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

Abstract

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