Spin divergence induced by exohedral modification: ESR study of Sc 3C2@C80 fulleropyrrolidine

Taishan Wang; Jingyi Wu; Wei Xu; Junfeng Xiang; Xin Lu; Bao Li; Li Jiang; Chunying Shu; Chunru Wang

doi:10.1002/anie.200906325

Spin divergence induced by exohedral modification: ESR study of Sc ₃C₂@C₈₀ fulleropyrrolidine

Taishan Wang^*, Jingyi Wu, Wei Xu, Junfeng Xiang, Xin Lu, Bao Li, Li Jiang, Chunying Shu, Chunru Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The paramagnetic properties of the endohedral fullerene Sc ₃C₂@C₈₀ are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc ₃C₂@C₈₀ fulleropyrrolidine and provide general Insight Into the addenddependent paramagnetic behavior of endohedral fullerenes. (Figure Presented)

Original language	English
Pages (from-to)	1786-1789
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	10
DOIs	https://doi.org/10.1002/anie.200906325
Publication status	Published - 1 Mar 2010
Externally published	Yes

Keywords

Carbides
Endohedral fullerenes
Epr spectroscopy
Exohedral addends
Prato reaction

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10.1002/anie.200906325

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title = "Spin divergence induced by exohedral modification: ESR study of Sc 3C2@C80 fulleropyrrolidine",

abstract = "The paramagnetic properties of the endohedral fullerene Sc 3C2@C80 are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc 3C2@C80 fulleropyrrolidine and provide general Insight Into the addenddependent paramagnetic behavior of endohedral fullerenes. (Figure Presented)",

keywords = "Carbides, Endohedral fullerenes, Epr spectroscopy, Exohedral addends, Prato reaction",

author = "Taishan Wang and Jingyi Wu and Wei Xu and Junfeng Xiang and Xin Lu and Bao Li and Li Jiang and Chunying Shu and Chunru Wang",

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T1 - Spin divergence induced by exohedral modification

T2 - ESR study of Sc 3C2@C80 fulleropyrrolidine

AU - Wang, Taishan

AU - Wu, Jingyi

AU - Xu, Wei

AU - Xiang, Junfeng

AU - Lu, Xin

AU - Li, Bao

AU - Jiang, Li

AU - Shu, Chunying

AU - Wang, Chunru

PY - 2010/3/1

Y1 - 2010/3/1

N2 - The paramagnetic properties of the endohedral fullerene Sc 3C2@C80 are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc 3C2@C80 fulleropyrrolidine and provide general Insight Into the addenddependent paramagnetic behavior of endohedral fullerenes. (Figure Presented)

AB - The paramagnetic properties of the endohedral fullerene Sc 3C2@C80 are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc 3C2@C80 fulleropyrrolidine and provide general Insight Into the addenddependent paramagnetic behavior of endohedral fullerenes. (Figure Presented)

KW - Carbides

KW - Endohedral fullerenes

KW - Epr spectroscopy

KW - Exohedral addends

KW - Prato reaction

UR - http://www.scopus.com/inward/record.url?scp=77749264686&partnerID=8YFLogxK

U2 - 10.1002/anie.200906325

DO - 10.1002/anie.200906325

M3 - Article

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AN - SCOPUS:77749264686

SN - 1433-7851

VL - 49

SP - 1786

EP - 1789

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 10

ER -

Spin divergence induced by exohedral modification: ESR study of Sc ₃C₂@C₈₀ fulleropyrrolidine

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Keywords

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