Spin-active metallofullerene stabilized by the core of an nc moiety

Yongqiang Feng; Taishan Wang; Jingyi Wu; Yihan Ma; Zhuxia Zhang; Li Jiang; Chunhua Ge; Chunying Shu; Chunru Wang

doi:10.1039/c3cc38445d

Spin-active metallofullerene stabilized by the core of an nc moiety

Yongqiang Feng, Taishan Wang^*, Jingyi Wu, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunhua Ge, Chunying Shu, Chunru Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A paramagnetic Sc₃NC@C₈₀ anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

Original language	English
Pages (from-to)	2148-2150
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	21
DOIs	https://doi.org/10.1039/c3cc38445d
Publication status	Published - 14 Feb 2013
Externally published	Yes

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title = "Spin-active metallofullerene stabilized by the core of an nc moiety",

abstract = "A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.",

author = "Yongqiang Feng and Taishan Wang and Jingyi Wu and Yihan Ma and Zhuxia Zhang and Li Jiang and Chunhua Ge and Chunying Shu and Chunru Wang",

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T1 - Spin-active metallofullerene stabilized by the core of an nc moiety

AU - Feng, Yongqiang

AU - Wang, Taishan

AU - Wu, Jingyi

AU - Ma, Yihan

AU - Zhang, Zhuxia

AU - Jiang, Li

AU - Ge, Chunhua

AU - Shu, Chunying

AU - Wang, Chunru

PY - 2013/2/14

Y1 - 2013/2/14

N2 - A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

AB - A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

UR - http://www.scopus.com/inward/record.url?scp=84874059510&partnerID=8YFLogxK

U2 - 10.1039/c3cc38445d

DO - 10.1039/c3cc38445d

M3 - Article

AN - SCOPUS:84874059510

SN - 1359-7345

VL - 49

SP - 2148

EP - 2150

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Spin-active metallofullerene stabilized by the core of an nc moiety

Abstract

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