@inproceedings{4a3e06ffe04245ceab29890acd2f46df,
title = "Spectrophotometric determination of kryptofix 2.2.2 using tcnq",
abstract = "The interactions of the electron donors kryptofix (K-222) with 7,7,8,8-Tetracyanoquinodimethane (TCNQ) were studied spectrophotometrically in aceton/water at several temperatures. The UV-vis spectra of the formed molecular charge transfer (CT) complexes were recorded. The molecular structures of the CT-complexes were independent of the position of the amino group on the K-222 and were formulated as [(K-222)(TCNQ)]. A spectrophotometric method for determination of K-222 was developed and validated for the quantitative analysis of K-222 in the radiopharmaceuticals. With an internal standard, the limit of quantitation for K-222 was 2 ug/ml. This is so far the most facile method for the determination of K-222. Excellent linearity (RSQ = 0.9997) was obtained over the range of 2.0-31 ug/ml. Good precision and accuracy were also observed. The method is amenable to the validation of radiosynthetic methods.",
keywords = "Kryptofix 2.2.2, Spectrophotometry, Tcnq",
author = "He, \{Mu Yi\} and Sun, \{Li Quan\} and Luo, \{Ai Qin\}",
year = "2012",
doi = "10.4028/www.scientific.net/AMR.581-582.1156",
language = "English",
isbn = "9783037855126",
series = "Advanced Materials Research",
number = "1",
pages = "1156--1159",
booktitle = "Frontiers of Materials, Chemical and Metallurgical Technologies",
edition = "1",
note = "2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012 ; Conference date: 12-10-2012 Through 13-10-2012",
}