Solubility of tetranitrodimerglycoluril (TNDGU) in different solvents at temperatures between 293.15 K and 313.15 K

Kejian Cui; Yumei Yang; Zihui Meng; Guangrui Xu; Zhibin Xu; Min Xue

doi:10.1021/je500392g

Solubility of tetranitrodimerglycoluril (TNDGU) in different solvents at temperatures between 293.15 K and 313.15 K

Kejian Cui
, Yumei Yang
, Zihui Meng^*
, Guangrui Xu
, Zhibin Xu
, Min Xue

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Tetranitrodimerglycoluril (TNDGU) is a newly developed insensitive energetic material. Its solubility in methanol, propanone, ethyl ethanoate, and ethanenitrile between 293.15 K and 313.15 K at atmospheric pressure was investigated by the gravimetric method. The order of the solubility of TNDGU is ethanenitrile > ethyl ethanoate ≈ propanone > methanol. The solubility of TNDGU increased with an increase of temperature. The enthalpy of dissolution in each solvent was also calculated according to a modified van't Hoff equation; the values are 25.18 kJ·mol^-1 for methanol, 41.26 kJ·mol^-1 for propanone, 34.70 kJ·mol^-1 for ethyl ethanoate, and 36.33 kJ·mol^-1 for ethanenitrile, respectively.

Original language	English
Pages (from-to)	2620-2622
Number of pages	3
Journal	Journal of Chemical and Engineering Data
Volume	59
Issue number	8
DOIs	https://doi.org/10.1021/je500392g
Publication status	Published - 14 Aug 2014
Externally published	Yes

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title = "Solubility of tetranitrodimerglycoluril (TNDGU) in different solvents at temperatures between 293.15 K and 313.15 K",

abstract = "Tetranitrodimerglycoluril (TNDGU) is a newly developed insensitive energetic material. Its solubility in methanol, propanone, ethyl ethanoate, and ethanenitrile between 293.15 K and 313.15 K at atmospheric pressure was investigated by the gravimetric method. The order of the solubility of TNDGU is ethanenitrile > ethyl ethanoate ≈ propanone > methanol. The solubility of TNDGU increased with an increase of temperature. The enthalpy of dissolution in each solvent was also calculated according to a modified van't Hoff equation; the values are 25.18 kJ·mol-1 for methanol, 41.26 kJ·mol-1 for propanone, 34.70 kJ·mol-1 for ethyl ethanoate, and 36.33 kJ·mol-1 for ethanenitrile, respectively.",

author = "Kejian Cui and Yumei Yang and Zihui Meng and Guangrui Xu and Zhibin Xu and Min Xue",

year = "2014",

month = aug,

day = "14",

doi = "10.1021/je500392g",

language = "English",

volume = "59",

pages = "2620--2622",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Solubility of tetranitrodimerglycoluril (TNDGU) in different solvents at temperatures between 293.15 K and 313.15 K

AU - Cui, Kejian

AU - Yang, Yumei

AU - Meng, Zihui

AU - Xu, Guangrui

AU - Xu, Zhibin

AU - Xue, Min

PY - 2014/8/14

Y1 - 2014/8/14

N2 - Tetranitrodimerglycoluril (TNDGU) is a newly developed insensitive energetic material. Its solubility in methanol, propanone, ethyl ethanoate, and ethanenitrile between 293.15 K and 313.15 K at atmospheric pressure was investigated by the gravimetric method. The order of the solubility of TNDGU is ethanenitrile > ethyl ethanoate ≈ propanone > methanol. The solubility of TNDGU increased with an increase of temperature. The enthalpy of dissolution in each solvent was also calculated according to a modified van't Hoff equation; the values are 25.18 kJ·mol-1 for methanol, 41.26 kJ·mol-1 for propanone, 34.70 kJ·mol-1 for ethyl ethanoate, and 36.33 kJ·mol-1 for ethanenitrile, respectively.

AB - Tetranitrodimerglycoluril (TNDGU) is a newly developed insensitive energetic material. Its solubility in methanol, propanone, ethyl ethanoate, and ethanenitrile between 293.15 K and 313.15 K at atmospheric pressure was investigated by the gravimetric method. The order of the solubility of TNDGU is ethanenitrile > ethyl ethanoate ≈ propanone > methanol. The solubility of TNDGU increased with an increase of temperature. The enthalpy of dissolution in each solvent was also calculated according to a modified van't Hoff equation; the values are 25.18 kJ·mol-1 for methanol, 41.26 kJ·mol-1 for propanone, 34.70 kJ·mol-1 for ethyl ethanoate, and 36.33 kJ·mol-1 for ethanenitrile, respectively.

UR - https://www.scopus.com/pages/publications/84906248423

U2 - 10.1021/je500392g

DO - 10.1021/je500392g

M3 - Article

AN - SCOPUS:84906248423

SN - 0021-9568

VL - 59

SP - 2620

EP - 2622

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 8

ER -

Solubility of tetranitrodimerglycoluril (TNDGU) in different solvents at temperatures between 293.15 K and 313.15 K

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