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Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model

  • Miyi Li
  • , Dana Constantinescu
  • , Lisheng Wang
  • , André Mohs
  • , Juürgen Gmehling*
  • *Corresponding author for this work
  • Beijing Institute of Technology
  • Institut Fuür Reine und Angewandte Chemie

Research output: Contribution to journalArticlepeer-review

Abstract

The solubilities of NaCl, KCl, LiCl, and LiBr in pure methanol, ethanol, and acetone were measured over a temperature range from 293.15 to 333.15 K. Furthermore salt solubilities in the mixed solvents (water + methanol, water + ethanol, water + acetone, methanol + ethanol, methanol + acetone, ethanol + acetone) were determined at 313.15 K. For a few systems solubility data are reported for the first time. In a few cases a comparison with published data stored in the Dortmund Data Bank (DDB)(1)showed disagreement. The LIQUAC model was used to correlate the experimental data. The calculated salt solubilities are in good agreement with the experimental results for the systems NaCl + water + methanol and KCl + water + methanol.

Original languageEnglish
Pages (from-to)4981-4988
Number of pages8
JournalIndustrial and Engineering Chemistry Research
Volume49
Issue number10
DOIs
Publication statusPublished - 19 May 2010
Externally publishedYes

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