TY - JOUR
T1 - Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model
AU - Li, Miyi
AU - Constantinescu, Dana
AU - Wang, Lisheng
AU - Mohs, André
AU - Gmehling, Juürgen
PY - 2010/5/19
Y1 - 2010/5/19
N2 - The solubilities of NaCl, KCl, LiCl, and LiBr in pure methanol, ethanol, and acetone were measured over a temperature range from 293.15 to 333.15 K. Furthermore salt solubilities in the mixed solvents (water + methanol, water + ethanol, water + acetone, methanol + ethanol, methanol + acetone, ethanol + acetone) were determined at 313.15 K. For a few systems solubility data are reported for the first time. In a few cases a comparison with published data stored in the Dortmund Data Bank (DDB)(1)showed disagreement. The LIQUAC model was used to correlate the experimental data. The calculated salt solubilities are in good agreement with the experimental results for the systems NaCl + water + methanol and KCl + water + methanol.
AB - The solubilities of NaCl, KCl, LiCl, and LiBr in pure methanol, ethanol, and acetone were measured over a temperature range from 293.15 to 333.15 K. Furthermore salt solubilities in the mixed solvents (water + methanol, water + ethanol, water + acetone, methanol + ethanol, methanol + acetone, ethanol + acetone) were determined at 313.15 K. For a few systems solubility data are reported for the first time. In a few cases a comparison with published data stored in the Dortmund Data Bank (DDB)(1)showed disagreement. The LIQUAC model was used to correlate the experimental data. The calculated salt solubilities are in good agreement with the experimental results for the systems NaCl + water + methanol and KCl + water + methanol.
UR - http://www.scopus.com/inward/record.url?scp=77952357813&partnerID=8YFLogxK
U2 - 10.1021/ie100027c
DO - 10.1021/ie100027c
M3 - Article
AN - SCOPUS:77952357813
SN - 0888-5885
VL - 49
SP - 4981
EP - 4988
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
IS - 10
ER -