Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K

Chunyuan Zhang; Shaohua Jin; Shusen Chen; Yan Zhang; Liang Qin; Xiaochun Wei; Qinghai Shu

doi:10.1021/acs.jced.6b00009

Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K

Chunyuan Zhang, Shaohua Jin, Shusen Chen, Yan Zhang, Liang Qin, Xiaochun Wei, Qinghai Shu^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.

Original language	English
Pages (from-to)	1873-1875
Number of pages	3
Journal	Journal of Chemical and Engineering Data
Volume	61
Issue number	5
DOIs	https://doi.org/10.1021/acs.jced.6b00009
Publication status	Published - 12 May 2016

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10.1021/acs.jced.6b00009

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title = "Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K",

abstract = "The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.",

author = "Chunyuan Zhang and Shaohua Jin and Shusen Chen and Yan Zhang and Liang Qin and Xiaochun Wei and Qinghai Shu",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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day = "12",

doi = "10.1021/acs.jced.6b00009",

language = "English",

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T1 - Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K

AU - Zhang, Chunyuan

AU - Jin, Shaohua

AU - Chen, Shusen

AU - Zhang, Yan

AU - Qin, Liang

AU - Wei, Xiaochun

AU - Shu, Qinghai

PY - 2016/5/12

Y1 - 2016/5/12

N2 - The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.

AB - The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.

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U2 - 10.1021/acs.jced.6b00009

DO - 10.1021/acs.jced.6b00009

M3 - Article

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SN - 0021-9568

VL - 61

SP - 1873

EP - 1875

JO - Journal of Chemical and Engineering Data

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IS - 5

ER -

Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K

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