Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene

Mengze Jia; Li Sun; Yunrui Chen; Jie Zhang

doi:10.1007/s40242-021-1226-z

Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene

Mengze Jia, Li Sun, Yunrui Chen, Jie Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A photoactive metal-organic complex [Zn₂(BCbpe)₂(p-DBC)₂]·5H₂O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.

Original language	English
Pages (from-to)	181-185
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	38
Issue number	1
DOIs	https://doi.org/10.1007/s40242-021-1226-z
Publication status	Published - Feb 2022

Keywords

Pyridinium
Solid-state photoreaction
[2+2] cycloaddition

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10.1007/s40242-021-1226-z

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title = "Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene",

abstract = "A photoactive metal-organic complex [Zn2(BCbpe)2(p-DBC)2]·5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.",

keywords = "Pyridinium, Solid-state photoreaction, [2+2] cycloaddition",

author = "Mengze Jia and Li Sun and Yunrui Chen and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2021, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH.",

year = "2022",

month = feb,

doi = "10.1007/s40242-021-1226-z",

language = "English",

volume = "38",

pages = "181--185",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer International Publishing AG",

number = "1",

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TY - JOUR

T1 - Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene

AU - Jia, Mengze

AU - Sun, Li

AU - Chen, Yunrui

AU - Zhang, Jie

PY - 2022/2

Y1 - 2022/2

N2 - A photoactive metal-organic complex [Zn2(BCbpe)2(p-DBC)2]·5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.

AB - A photoactive metal-organic complex [Zn2(BCbpe)2(p-DBC)2]·5H2O(1) has been synthesized based on an olefin-containing pyridinium compound, 1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl] pyridinium chloride(HBCbpeCl), and characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. In the solid state, the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction, undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.

KW - Pyridinium

KW - Solid-state photoreaction

KW - [2+2] cycloaddition

UR - https://www.scopus.com/pages/publications/85111100001

U2 - 10.1007/s40242-021-1226-z

DO - 10.1007/s40242-021-1226-z

M3 - Article

AN - SCOPUS:85111100001

SN - 1005-9040

VL - 38

SP - 181

EP - 185

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 1

ER -

Solid-state [2+2] Photocycloaddition Reaction of Zinc(II) Complex Based on Quaternized 1,2-Bis(4′-pyridyl)ethylene

Abstract

Keywords

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