Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface

Min Li; Ke Deng; Sheng Bin Lei; Yan Lian Yang; Tai Shan Wang; Yong Tao Shen; Chun Ru Wang; Qing Dao Zeng; Chen Wang

doi:10.1002/anie.200802518

Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface

Min Li^*
, Ke Deng
, Sheng Bin Lei
, Yan Lian Yang
, Tai Shan Wang
, Yong Tao Shen
, Chun Ru Wang
, Qing Dao Zeng
, Chen Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

131 Citations (Scopus)

Abstract

(Figure Presented) A selective invitation: A 2D hydrogen-bonded porous network formed by an azobenzene derivative (NN4A) contains two different types of cavities and is shown to selectively accommodate fullerenes C₈₀ and Sc₃N@C₈₀ (see picture). Highly ordered fullerene arrays are constructed at the liquid-solid interface of graphite by coadsorption of fullerenes and NN4A. While C₆₀ occupies both types of cavity, C₈₀ and Sc₃N@C₈₀ are only immobilized in one cavity type.

Original language	English
Pages (from-to)	6717-6721
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	35
DOIs	https://doi.org/10.1002/anie.200802518
Publication status	Published - 18 Aug 2008
Externally published	Yes

Keywords

Azobenzenes
Fullerenes
Scanning probe microscopy
Self-assembly
Site selectivity

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10.1002/anie.200802518

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title = "Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface",

abstract = "(Figure Presented) A selective invitation: A 2D hydrogen-bonded porous network formed by an azobenzene derivative (NN4A) contains two different types of cavities and is shown to selectively accommodate fullerenes C80 and Sc3N@C80 (see picture). Highly ordered fullerene arrays are constructed at the liquid-solid interface of graphite by coadsorption of fullerenes and NN4A. While C60 occupies both types of cavity, C80 and Sc3N@C80 are only immobilized in one cavity type.",

keywords = "Azobenzenes, Fullerenes, Scanning probe microscopy, Self-assembly, Site selectivity",

author = "Min Li and Ke Deng and Lei, \{Sheng Bin\} and Yang, \{Yan Lian\} and Wang, \{Tai Shan\} and Shen, \{Yong Tao\} and Wang, \{Chun Ru\} and Zeng, \{Qing Dao\} and Chen Wang",

year = "2008",

month = aug,

day = "18",

doi = "10.1002/anie.200802518",

language = "English",

volume = "47",

pages = "6717--6721",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

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}

TY - JOUR

T1 - Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface

AU - Li, Min

AU - Deng, Ke

AU - Lei, Sheng Bin

AU - Yang, Yan Lian

AU - Wang, Tai Shan

AU - Shen, Yong Tao

AU - Wang, Chun Ru

AU - Zeng, Qing Dao

AU - Wang, Chen

PY - 2008/8/18

Y1 - 2008/8/18

N2 - (Figure Presented) A selective invitation: A 2D hydrogen-bonded porous network formed by an azobenzene derivative (NN4A) contains two different types of cavities and is shown to selectively accommodate fullerenes C80 and Sc3N@C80 (see picture). Highly ordered fullerene arrays are constructed at the liquid-solid interface of graphite by coadsorption of fullerenes and NN4A. While C60 occupies both types of cavity, C80 and Sc3N@C80 are only immobilized in one cavity type.

AB - (Figure Presented) A selective invitation: A 2D hydrogen-bonded porous network formed by an azobenzene derivative (NN4A) contains two different types of cavities and is shown to selectively accommodate fullerenes C80 and Sc3N@C80 (see picture). Highly ordered fullerene arrays are constructed at the liquid-solid interface of graphite by coadsorption of fullerenes and NN4A. While C60 occupies both types of cavity, C80 and Sc3N@C80 are only immobilized in one cavity type.

KW - Azobenzenes

KW - Fullerenes

KW - Scanning probe microscopy

KW - Self-assembly

KW - Site selectivity

UR - https://www.scopus.com/pages/publications/53249084425

U2 - 10.1002/anie.200802518

DO - 10.1002/anie.200802518

M3 - Article

AN - SCOPUS:53249084425

SN - 1433-7851

VL - 47

SP - 6717

EP - 6721

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 35

ER -

Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface

Abstract

Keywords

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