Single-atom Ru on Al2O3for highly active and selective 1,2-Dichloroethane catalytic degradation

Jiajing Pei; Bo Peng; He Lin; Wenxing Chen; Yu Wang; Juncai Dong; Junjie Mao; Dianzeng Jia; Wei Zhu; Zhongbin Zhuang

doi:10.1021/acsami.1c08471

Single-atom Ru on Al₂O₃for highly active and selective 1,2-Dichloroethane catalytic degradation

Jiajing Pei
, Bo Peng
, He Lin^*
, Wenxing Chen
, Yu Wang
, Juncai Dong
, Junjie Mao
, Dianzeng Jia
, Wei Zhu^*
, Zhongbin Zhuang^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

1,2-Dichloroethane (1,2-DCE) is a toxic volatile organic compound, which is harmful to the environment and human health. Herein, we develop a single-atom Ru catalyst anchored on the mesoporous schistose ?-Al2O3 (Ru SACs/m-?-Al2O3) to enhance the catalytic activity and selectivity toward 1,2-DCE degradation. The Ru SACs/m-?-Al2O3 shows low T50 and T90 (the temperature for 50 and 90% conversion) of 215 and 289 °C, which are lower than those for Ru NPs/m-?-Al2O3 (291 and 374 °C) and pristine m-?-Al2O3 (323 and 386 °C). The degradation products are mainly CO2 (>94%) and HCl (>90%) by using the Ru SACs/m-?-Al2O3 catalyst, and almost no byproducts are detected. Furthermore, Ru SACs/m-?-Al2O3 also presents excellent anti-chlorine poisoning effect and water resistance during the stability test. This work may shed light on the development of efficient single-atom catalysts for the degradation of industrial pollutants.

Original language	English
Pages (from-to)	53683-53690
Number of pages	8
Journal	ACS Applied Materials and Interfaces
Volume	13
Issue number	45
DOIs	https://doi.org/10.1021/acsami.1c08471
Publication status	Published - 17 Nov 2021

Keywords

1,2-dichloroethane
C-Cl cleavage
Ru single atom
catalytic activity and selectivity
dechlorination process

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Access to Document

10.1021/acsami.1c08471

Cite this

@article{20cec5cbf2644429a552fa6e5ffd4d0c,

title = "Single-atom Ru on Al2O3for highly active and selective 1,2-Dichloroethane catalytic degradation",

abstract = "1,2-Dichloroethane (1,2-DCE) is a toxic volatile organic compound, which is harmful to the environment and human health. Herein, we develop a single-atom Ru catalyst anchored on the mesoporous schistose ?-Al2O3 (Ru SACs/m-?-Al2O3) to enhance the catalytic activity and selectivity toward 1,2-DCE degradation. The Ru SACs/m-?-Al2O3 shows low T50 and T90 (the temperature for 50 and 90\% conversion) of 215 and 289 °C, which are lower than those for Ru NPs/m-?-Al2O3 (291 and 374 °C) and pristine m-?-Al2O3 (323 and 386 °C). The degradation products are mainly CO2 (>94\%) and HCl (>90\%) by using the Ru SACs/m-?-Al2O3 catalyst, and almost no byproducts are detected. Furthermore, Ru SACs/m-?-Al2O3 also presents excellent anti-chlorine poisoning effect and water resistance during the stability test. This work may shed light on the development of efficient single-atom catalysts for the degradation of industrial pollutants.",

keywords = "1,2-dichloroethane, C-Cl cleavage, Ru single atom, catalytic activity and selectivity, dechlorination process",

author = "Jiajing Pei and Bo Peng and He Lin and Wenxing Chen and Yu Wang and Juncai Dong and Junjie Mao and Dianzeng Jia and Wei Zhu and Zhongbin Zhuang",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

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doi = "10.1021/acsami.1c08471",

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T1 - Single-atom Ru on Al2O3for highly active and selective 1,2-Dichloroethane catalytic degradation

AU - Pei, Jiajing

AU - Peng, Bo

AU - Lin, He

AU - Chen, Wenxing

AU - Wang, Yu

AU - Dong, Juncai

AU - Mao, Junjie

AU - Jia, Dianzeng

AU - Zhu, Wei

AU - Zhuang, Zhongbin

PY - 2021/11/17

Y1 - 2021/11/17

N2 - 1,2-Dichloroethane (1,2-DCE) is a toxic volatile organic compound, which is harmful to the environment and human health. Herein, we develop a single-atom Ru catalyst anchored on the mesoporous schistose ?-Al2O3 (Ru SACs/m-?-Al2O3) to enhance the catalytic activity and selectivity toward 1,2-DCE degradation. The Ru SACs/m-?-Al2O3 shows low T50 and T90 (the temperature for 50 and 90% conversion) of 215 and 289 °C, which are lower than those for Ru NPs/m-?-Al2O3 (291 and 374 °C) and pristine m-?-Al2O3 (323 and 386 °C). The degradation products are mainly CO2 (>94%) and HCl (>90%) by using the Ru SACs/m-?-Al2O3 catalyst, and almost no byproducts are detected. Furthermore, Ru SACs/m-?-Al2O3 also presents excellent anti-chlorine poisoning effect and water resistance during the stability test. This work may shed light on the development of efficient single-atom catalysts for the degradation of industrial pollutants.

AB - 1,2-Dichloroethane (1,2-DCE) is a toxic volatile organic compound, which is harmful to the environment and human health. Herein, we develop a single-atom Ru catalyst anchored on the mesoporous schistose ?-Al2O3 (Ru SACs/m-?-Al2O3) to enhance the catalytic activity and selectivity toward 1,2-DCE degradation. The Ru SACs/m-?-Al2O3 shows low T50 and T90 (the temperature for 50 and 90% conversion) of 215 and 289 °C, which are lower than those for Ru NPs/m-?-Al2O3 (291 and 374 °C) and pristine m-?-Al2O3 (323 and 386 °C). The degradation products are mainly CO2 (>94%) and HCl (>90%) by using the Ru SACs/m-?-Al2O3 catalyst, and almost no byproducts are detected. Furthermore, Ru SACs/m-?-Al2O3 also presents excellent anti-chlorine poisoning effect and water resistance during the stability test. This work may shed light on the development of efficient single-atom catalysts for the degradation of industrial pollutants.

KW - 1,2-dichloroethane

KW - C-Cl cleavage

KW - Ru single atom

KW - catalytic activity and selectivity

KW - dechlorination process

UR - https://www.scopus.com/pages/publications/85119260446

U2 - 10.1021/acsami.1c08471

DO - 10.1021/acsami.1c08471

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