Silver-Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Kai Sun; Ya Feng Si; Xiao Lan Chen; Qi Yan Lv; Nan Jiang; Shan Shan Wang; Yu Yu Peng; Ling Bo Qu; Bing Yu

doi:10.1002/adsc.201900691

Silver-Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Kai Sun
, Ya Feng Si
, Xiao Lan Chen^*
, Qi Yan Lv
, Nan Jiang
, Shan Shan Wang
, Yu Yu Peng
, Ling Bo Qu
, Bing Yu

^*Corresponding author for this work

School of Education

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

A convenient radical cascade cyclization of aniline-linked 1,7-enynes with 1,3-dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO₃/K₂S₂O₈. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields. (Figure presented.).

Original language	English
Pages (from-to)	4483-4488
Number of pages	6
Journal	Advanced Synthesis and Catalysis
Volume	361
Issue number	19
DOIs	https://doi.org/10.1002/adsc.201900691
Publication status	Published - 8 Oct 2019

Keywords

1,3-Dicarbonyl compound
Cyclopenta[c]quinolines
Radical cascade reaction
Unactivated alkenes

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10.1002/adsc.201900691

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title = "Silver-Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines",

abstract = "A convenient radical cascade cyclization of aniline-linked 1,7-enynes with 1,3-dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO3/K2S2O8. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields. (Figure presented.).",

keywords = "1,3-Dicarbonyl compound, Cyclopenta[c]quinolines, Radical cascade reaction, Unactivated alkenes",

author = "Kai Sun and Si, \{Ya Feng\} and Chen, \{Xiao Lan\} and Lv, \{Qi Yan\} and Nan Jiang and Wang, \{Shan Shan\} and Peng, \{Yu Yu\} and Qu, \{Ling Bo\} and Bing Yu",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

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day = "8",

doi = "10.1002/adsc.201900691",

language = "English",

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TY - JOUR

T1 - Silver-Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

AU - Sun, Kai

AU - Si, Ya Feng

AU - Chen, Xiao Lan

AU - Lv, Qi Yan

AU - Jiang, Nan

AU - Wang, Shan Shan

AU - Peng, Yu Yu

AU - Qu, Ling Bo

AU - Yu, Bing

PY - 2019/10/8

Y1 - 2019/10/8

N2 - A convenient radical cascade cyclization of aniline-linked 1,7-enynes with 1,3-dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO3/K2S2O8. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields. (Figure presented.).

AB - A convenient radical cascade cyclization of aniline-linked 1,7-enynes with 1,3-dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO3/K2S2O8. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields. (Figure presented.).

KW - 1,3-Dicarbonyl compound

KW - Cyclopenta[c]quinolines

KW - Radical cascade reaction

KW - Unactivated alkenes

UR - https://www.scopus.com/pages/publications/85070749330

U2 - 10.1002/adsc.201900691

DO - 10.1002/adsc.201900691

M3 - Article

AN - SCOPUS:85070749330

SN - 1615-4150

VL - 361

SP - 4483

EP - 4488

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 19

ER -

Silver-Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Abstract

Keywords

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