Silicic Acid Removal by Metal-Organic Frameworks for Silica-Scale Mitigation in Reverse Osmosis

Rui Guo; Jun Zhang; Taona Nashel Mufanebadza; Xinxia Tian; Lixin Xie; Song Zhao

doi:10.3390/membranes13010078

Silicic Acid Removal by Metal-Organic Frameworks for Silica-Scale Mitigation in Reverse Osmosis

Rui Guo
, Jun Zhang
, Taona Nashel Mufanebadza
, Xinxia Tian^*
, Lixin Xie^*
, Song Zhao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reverse osmosis (RO) membranes are susceptible to silica scaling, resulting in irreversible degradation of membrane performance. This work covered the fabrication of MIL-101(Fe) for silicic acid adsorption to alleviate the silica scaling of RO membranes. The effect of pH, mixing time and initial concentration on silicic acid adsorption of MIL-101(Fe) was appraised in detail. The adsorption experiments demonstrated that MIL-101(Fe) possessed an excellent adsorption ability for silicic acid with the maximum adsorption capacity reaching 220.1 mgSiO₂·g⁻¹. Data fitting confirmed the pseudo-second-order equation and Freundlich equation were consistent with silicic acid adsorption on MIL-101(Fe). Finally, a simulated anti-scaling experiment was carried out using a feed solution pretreated by MIL-101(Fe) adsorption, and the permeance exhibited a much lower decline after 24 h filtration, confirming that MIL-101(Fe) exhibits an excellent application potential for silica-scale mitigation in RO systems.

Original language	English
Article number	78
Journal	Membranes
Volume	13
Issue number	1
DOIs	https://doi.org/10.3390/membranes13010078
Publication status	Published - Jan 2023
Externally published	Yes

Keywords

MIL-101(Fe) MOF
adsorption
pretreatment
reverse osmosis
silicic acid removal

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10.3390/membranes13010078

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@article{7a7ca9aa744d42c191d43bcc32635768,

title = "Silicic Acid Removal by Metal-Organic Frameworks for Silica-Scale Mitigation in Reverse Osmosis",

abstract = "Reverse osmosis (RO) membranes are susceptible to silica scaling, resulting in irreversible degradation of membrane performance. This work covered the fabrication of MIL-101(Fe) for silicic acid adsorption to alleviate the silica scaling of RO membranes. The effect of pH, mixing time and initial concentration on silicic acid adsorption of MIL-101(Fe) was appraised in detail. The adsorption experiments demonstrated that MIL-101(Fe) possessed an excellent adsorption ability for silicic acid with the maximum adsorption capacity reaching 220.1 mgSiO2·g−1. Data fitting confirmed the pseudo-second-order equation and Freundlich equation were consistent with silicic acid adsorption on MIL-101(Fe). Finally, a simulated anti-scaling experiment was carried out using a feed solution pretreated by MIL-101(Fe) adsorption, and the permeance exhibited a much lower decline after 24 h filtration, confirming that MIL-101(Fe) exhibits an excellent application potential for silica-scale mitigation in RO systems.",

keywords = "MIL-101(Fe) MOF, adsorption, pretreatment, reverse osmosis, silicic acid removal",

author = "Rui Guo and Jun Zhang and Mufanebadza, \{Taona Nashel\} and Xinxia Tian and Lixin Xie and Song Zhao",

note = "Publisher Copyright: {\textcopyright} 2023 by the authors.",

year = "2023",

month = jan,

doi = "10.3390/membranes13010078",

language = "English",

volume = "13",

journal = "Membranes",

issn = "2077-0375",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "1",

}

TY - JOUR

T1 - Silicic Acid Removal by Metal-Organic Frameworks for Silica-Scale Mitigation in Reverse Osmosis

AU - Guo, Rui

AU - Zhang, Jun

AU - Mufanebadza, Taona Nashel

AU - Tian, Xinxia

AU - Xie, Lixin

AU - Zhao, Song

PY - 2023/1

Y1 - 2023/1

N2 - Reverse osmosis (RO) membranes are susceptible to silica scaling, resulting in irreversible degradation of membrane performance. This work covered the fabrication of MIL-101(Fe) for silicic acid adsorption to alleviate the silica scaling of RO membranes. The effect of pH, mixing time and initial concentration on silicic acid adsorption of MIL-101(Fe) was appraised in detail. The adsorption experiments demonstrated that MIL-101(Fe) possessed an excellent adsorption ability for silicic acid with the maximum adsorption capacity reaching 220.1 mgSiO2·g−1. Data fitting confirmed the pseudo-second-order equation and Freundlich equation were consistent with silicic acid adsorption on MIL-101(Fe). Finally, a simulated anti-scaling experiment was carried out using a feed solution pretreated by MIL-101(Fe) adsorption, and the permeance exhibited a much lower decline after 24 h filtration, confirming that MIL-101(Fe) exhibits an excellent application potential for silica-scale mitigation in RO systems.

AB - Reverse osmosis (RO) membranes are susceptible to silica scaling, resulting in irreversible degradation of membrane performance. This work covered the fabrication of MIL-101(Fe) for silicic acid adsorption to alleviate the silica scaling of RO membranes. The effect of pH, mixing time and initial concentration on silicic acid adsorption of MIL-101(Fe) was appraised in detail. The adsorption experiments demonstrated that MIL-101(Fe) possessed an excellent adsorption ability for silicic acid with the maximum adsorption capacity reaching 220.1 mgSiO2·g−1. Data fitting confirmed the pseudo-second-order equation and Freundlich equation were consistent with silicic acid adsorption on MIL-101(Fe). Finally, a simulated anti-scaling experiment was carried out using a feed solution pretreated by MIL-101(Fe) adsorption, and the permeance exhibited a much lower decline after 24 h filtration, confirming that MIL-101(Fe) exhibits an excellent application potential for silica-scale mitigation in RO systems.

KW - MIL-101(Fe) MOF

KW - adsorption

KW - pretreatment

KW - reverse osmosis

KW - silicic acid removal

UR - https://www.scopus.com/pages/publications/85146536926

U2 - 10.3390/membranes13010078

DO - 10.3390/membranes13010078

M3 - Article

AN - SCOPUS:85146536926

SN - 2077-0375

VL - 13

JO - Membranes

JF - Membranes

IS - 1

M1 - 78

ER -

Silicic Acid Removal by Metal-Organic Frameworks for Silica-Scale Mitigation in Reverse Osmosis

Abstract

Keywords

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