Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

Bao Li; Jun Tao; Hao Ling Sun; Osamu Sato; Rong Bin Huang; Lan Sun Zheng

doi:10.1039/b801171k

Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

Bao Li
, Jun Tao^*
, Hao Ling Sun
, Osamu Sato
, Rong Bin Huang
, Lan Sun Zheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

A cobalt complex [{Co(dpqa)}₂(dhbq)](PF₆)₃ (1(PF₆)₃, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

Original language	English
Pages (from-to)	2269-2271
Number of pages	3
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/b801171k
Publication status	Published - 2008
Externally published	Yes

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@article{8088b1c092154fd8a7da3e38f08032ba,

title = "Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex",

abstract = "A cobalt complex [\{Co(dpqa)\}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.",

author = "Bao Li and Jun Tao and Sun, \{Hao Ling\} and Osamu Sato and Huang, \{Rong Bin\} and Zheng, \{Lan Sun\}",

year = "2008",

doi = "10.1039/b801171k",

language = "English",

pages = "2269--2271",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

AU - Li, Bao

AU - Tao, Jun

AU - Sun, Hao Ling

AU - Sato, Osamu

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2008

Y1 - 2008

N2 - A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

AB - A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

UR - https://www.scopus.com/pages/publications/46749091636

U2 - 10.1039/b801171k

DO - 10.1039/b801171k

M3 - Article

AN - SCOPUS:46749091636

SN - 1359-7345

SP - 2269

EP - 2271

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

Abstract

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