Shape-persistent, truxene-based, nano-sized bisterpyridine ruthenium(ii) complexes: Synthesis and photophysical propertiesa

Jin Liang Wang; Yi Tsu Chan; Charles N. Moorefield; Jian Pei; David A. Modarelli; Natalie C. Romano; George R. Newkome

doi:10.1002/marc.200900874

Shape-persistent, truxene-based, nano-sized bisterpyridine ruthenium(ii) complexes: Synthesis and photophysical properties^a

Jin Liang Wang, Yi Tsu Chan, Charles N. Moorefield, Jian Pei, David A. Modarelli, Natalie C. Romano, George R. Newkome

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

(Figure Presented) A new series of shape-persistent metallomacromolecules G0 and G1 as well as corresponding ligands, based on thiophene-functionalized bisterpyridine-Ru(II) with truxene moieties, as the nodes, were developed. All new compounds were fully characterized by ¹H, COSY, and ¹³C NMR, as well as MALDI-TOF MS. Their photophysical properties revealed that the branched scaffold resulted in high molar absorption coefficients and broad absorption making these materials potential candidates for light-harvesting.

Original language	English
Pages (from-to)	850-855
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	31
Issue number	9-10
DOIs	https://doi.org/10.1002/marc.200900874
Publication status	Published - 12 May 2010
Externally published	Yes

Keywords

Branched
Dendrimers
Metallomacromolecule
Shape-persistent
Terpyridine

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10.1002/marc.200900874

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abstract = "(Figure Presented) A new series of shape-persistent metallomacromolecules G0 and G1 as well as corresponding ligands, based on thiophene-functionalized bisterpyridine-Ru(II) with truxene moieties, as the nodes, were developed. All new compounds were fully characterized by 1H, COSY, and 13C NMR, as well as MALDI-TOF MS. Their photophysical properties revealed that the branched scaffold resulted in high molar absorption coefficients and broad absorption making these materials potential candidates for light-harvesting.",

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T1 - Shape-persistent, truxene-based, nano-sized bisterpyridine ruthenium(ii) complexes

T2 - Synthesis and photophysical propertiesa

AU - Wang, Jin Liang

AU - Chan, Yi Tsu

AU - Moorefield, Charles N.

AU - Pei, Jian

AU - Modarelli, David A.

AU - Romano, Natalie C.

AU - Newkome, George R.

PY - 2010/5/12

Y1 - 2010/5/12

N2 - (Figure Presented) A new series of shape-persistent metallomacromolecules G0 and G1 as well as corresponding ligands, based on thiophene-functionalized bisterpyridine-Ru(II) with truxene moieties, as the nodes, were developed. All new compounds were fully characterized by 1H, COSY, and 13C NMR, as well as MALDI-TOF MS. Their photophysical properties revealed that the branched scaffold resulted in high molar absorption coefficients and broad absorption making these materials potential candidates for light-harvesting.

AB - (Figure Presented) A new series of shape-persistent metallomacromolecules G0 and G1 as well as corresponding ligands, based on thiophene-functionalized bisterpyridine-Ru(II) with truxene moieties, as the nodes, were developed. All new compounds were fully characterized by 1H, COSY, and 13C NMR, as well as MALDI-TOF MS. Their photophysical properties revealed that the branched scaffold resulted in high molar absorption coefficients and broad absorption making these materials potential candidates for light-harvesting.

KW - Branched

KW - Dendrimers

KW - Metallomacromolecule

KW - Shape-persistent

KW - Terpyridine

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DO - 10.1002/marc.200900874

M3 - Article

AN - SCOPUS:77952610993

SN - 1022-1336

VL - 31

SP - 850

EP - 855

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9-10

ER -

Shape-persistent, truxene-based, nano-sized bisterpyridine ruthenium(ii) complexes: Synthesis and photophysical properties^a

Abstract

Keywords

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