Separation of TAT and TRAT using HPLC

Zhong Liang Lou; Zi Hui Meng; Wen Jun Meng; Peng Wang

doi:10.3969/j.issn.1006-9941.2010.02.023

Separation of TAT and TRAT using HPLC

Zhong Liang Lou
, Zi Hui Meng^*
, Wen Jun Meng
, Peng Wang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A high performance liquid chromatography (HPLC) method was developed for the separation of 1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT) and 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT), which are the intermediates for the synthetic reaction of 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX). The chromatograms of TAT and TRAT were further confirmed by high performance liquid chromatography-mass spectrometry (HPLC-MS). The optimal separation conditions are: sillca column (4.6 mm × 250 mm i. d., 5 μm), mobile phase: acetonitrile/water (75/25, V/V); the flow rate is 1.0 mL · min^-1, the wavelength is 215 nm, the injection volume is 20 μL.

Original language	English
Pages (from-to)	226-228
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	18
Issue number	2
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2010.02.023
Publication status	Published - Apr 2010
Externally published	Yes

Keywords

1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT)
1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX)
1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT)
1, 3, 5-trinitro-1, 3, 5-triazacyclohexane (RDX)
Analytic chemistry
High

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10.3969/j.issn.1006-9941.2010.02.023

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@article{37b9bcecb02b4376ae37cbd73ff49404,

title = "Separation of TAT and TRAT using HPLC",

abstract = "A high performance liquid chromatography (HPLC) method was developed for the separation of 1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT) and 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT), which are the intermediates for the synthetic reaction of 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX). The chromatograms of TAT and TRAT were further confirmed by high performance liquid chromatography-mass spectrometry (HPLC-MS). The optimal separation conditions are: sillca column (4.6 mm {\texttimes} 250 mm i. d., 5 μm), mobile phase: acetonitrile/water (75/25, V/V); the flow rate is 1.0 mL · min-1, the wavelength is 215 nm, the injection volume is 20 μL.",

keywords = "1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT), 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX), 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT), 1, 3, 5-trinitro-1, 3, 5-triazacyclohexane (RDX), Analytic chemistry, High",

author = "Lou, \{Zhong Liang\} and Meng, \{Zi Hui\} and Meng, \{Wen Jun\} and Peng Wang",

year = "2010",

month = apr,

doi = "10.3969/j.issn.1006-9941.2010.02.023",

language = "English",

volume = "18",

pages = "226--228",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "2",

}

TY - JOUR

T1 - Separation of TAT and TRAT using HPLC

AU - Lou, Zhong Liang

AU - Meng, Zi Hui

AU - Meng, Wen Jun

AU - Wang, Peng

PY - 2010/4

Y1 - 2010/4

N2 - A high performance liquid chromatography (HPLC) method was developed for the separation of 1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT) and 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT), which are the intermediates for the synthetic reaction of 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX). The chromatograms of TAT and TRAT were further confirmed by high performance liquid chromatography-mass spectrometry (HPLC-MS). The optimal separation conditions are: sillca column (4.6 mm × 250 mm i. d., 5 μm), mobile phase: acetonitrile/water (75/25, V/V); the flow rate is 1.0 mL · min-1, the wavelength is 215 nm, the injection volume is 20 μL.

AB - A high performance liquid chromatography (HPLC) method was developed for the separation of 1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT) and 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT), which are the intermediates for the synthetic reaction of 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX). The chromatograms of TAT and TRAT were further confirmed by high performance liquid chromatography-mass spectrometry (HPLC-MS). The optimal separation conditions are: sillca column (4.6 mm × 250 mm i. d., 5 μm), mobile phase: acetonitrile/water (75/25, V/V); the flow rate is 1.0 mL · min-1, the wavelength is 215 nm, the injection volume is 20 μL.

KW - 1, 3, 5, 7-tetraacetyl-1, 3, 5, 7-tetraazacyclooctane (TAT)

KW - 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazacyclooctane (HMX)

KW - 1, 3, 5-triacetyl-1, 3, 5-triazacyclohexane (TRAT)

KW - 1, 3, 5-trinitro-1, 3, 5-triazacyclohexane (RDX)

KW - Analytic chemistry

KW - High

UR - https://www.scopus.com/pages/publications/77952838766

U2 - 10.3969/j.issn.1006-9941.2010.02.023

DO - 10.3969/j.issn.1006-9941.2010.02.023

M3 - Article

AN - SCOPUS:77952838766

SN - 1006-9941

VL - 18

SP - 226

EP - 228

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 2

ER -

Separation of TAT and TRAT using HPLC

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