Semicarbazide as capable ligand for mutual transformation between MOF and chelate

Rui Zhang; Wen Chao Tong; Yan Lan Wang; Jian Chao Liu; Li Yang

doi:10.3233/MGC-160227

Semicarbazide as capable ligand for mutual transformation between MOF and chelate

Rui Zhang
, Wen Chao Tong^*
, Yan Lan Wang
, Jian Chao Liu
, Li Yang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A novel transition metal chelate Cd(SCZ)₂Cl₂ (SCZ=semicarbazide) was synthesized from a known 1D metal-organic framework (MOF) Cd(SCZ)Cl₂ and fully characterized by elemental analysis and FTIR spectroscopy. Then the 1D MOF Cd(SCZ)Cl₂ was regained by adding CdCl₂ to the chelate Cd(SCZ)₂Cl₂. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)₂Cl₂ crystallizes in orthorhombic Pbcn space group. Differential scanning calorimetry (DSC) was applied to assess the thermal decomposition behavior of Cd(SCZ)₂Cl₂. The non-isothermal kinetics parameters of Cd(SCZ)₂Cl₂ were calculated by the methods of Kissinger and Ozawa-Doyle, respectively.

Original language	English
Pages (from-to)	77-84
Number of pages	8
Journal	Main Group Chemistry
Volume	16
Issue number	2
DOIs	https://doi.org/10.3233/MGC-160227
Publication status	Published - 2017

Keywords

Cadmium(II)
crystal structure
semicarbazide
thermal analysis

Access to Document

10.3233/MGC-160227

Cite this

@article{7b8bff17a83947db90c688570878d47d,

title = "Semicarbazide as capable ligand for mutual transformation between MOF and chelate",

abstract = "A novel transition metal chelate Cd(SCZ)2Cl2 (SCZ=semicarbazide) was synthesized from a known 1D metal-organic framework (MOF) Cd(SCZ)Cl2 and fully characterized by elemental analysis and FTIR spectroscopy. Then the 1D MOF Cd(SCZ)Cl2 was regained by adding CdCl2 to the chelate Cd(SCZ)2Cl2. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)2Cl2 crystallizes in orthorhombic Pbcn space group. Differential scanning calorimetry (DSC) was applied to assess the thermal decomposition behavior of Cd(SCZ)2Cl2. The non-isothermal kinetics parameters of Cd(SCZ)2Cl2 were calculated by the methods of Kissinger and Ozawa-Doyle, respectively.",

keywords = "Cadmium(II), crystal structure, semicarbazide, thermal analysis",

author = "Rui Zhang and Tong, \{Wen Chao\} and Wang, \{Yan Lan\} and Liu, \{Jian Chao\} and Li Yang",

year = "2017",

doi = "10.3233/MGC-160227",

language = "English",

volume = "16",

pages = "77--84",

journal = "Main Group Chemistry",

issn = "1024-1221",

publisher = "SAGE Publications Ltd",

number = "2",

}

TY - JOUR

T1 - Semicarbazide as capable ligand for mutual transformation between MOF and chelate

AU - Zhang, Rui

AU - Tong, Wen Chao

AU - Wang, Yan Lan

AU - Liu, Jian Chao

AU - Yang, Li

PY - 2017

Y1 - 2017

N2 - A novel transition metal chelate Cd(SCZ)2Cl2 (SCZ=semicarbazide) was synthesized from a known 1D metal-organic framework (MOF) Cd(SCZ)Cl2 and fully characterized by elemental analysis and FTIR spectroscopy. Then the 1D MOF Cd(SCZ)Cl2 was regained by adding CdCl2 to the chelate Cd(SCZ)2Cl2. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)2Cl2 crystallizes in orthorhombic Pbcn space group. Differential scanning calorimetry (DSC) was applied to assess the thermal decomposition behavior of Cd(SCZ)2Cl2. The non-isothermal kinetics parameters of Cd(SCZ)2Cl2 were calculated by the methods of Kissinger and Ozawa-Doyle, respectively.

AB - A novel transition metal chelate Cd(SCZ)2Cl2 (SCZ=semicarbazide) was synthesized from a known 1D metal-organic framework (MOF) Cd(SCZ)Cl2 and fully characterized by elemental analysis and FTIR spectroscopy. Then the 1D MOF Cd(SCZ)Cl2 was regained by adding CdCl2 to the chelate Cd(SCZ)2Cl2. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)2Cl2 crystallizes in orthorhombic Pbcn space group. Differential scanning calorimetry (DSC) was applied to assess the thermal decomposition behavior of Cd(SCZ)2Cl2. The non-isothermal kinetics parameters of Cd(SCZ)2Cl2 were calculated by the methods of Kissinger and Ozawa-Doyle, respectively.

KW - Cadmium(II)

KW - crystal structure

KW - semicarbazide

KW - thermal analysis

UR - https://www.scopus.com/pages/publications/85021777637

U2 - 10.3233/MGC-160227

DO - 10.3233/MGC-160227

M3 - Article

AN - SCOPUS:85021777637

SN - 1024-1221

VL - 16

SP - 77

EP - 84

JO - Main Group Chemistry

JF - Main Group Chemistry

IS - 2

ER -

Semicarbazide as capable ligand for mutual transformation between MOF and chelate

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this