Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

Ni Zhen; Jing Dong; Zhengguo Lin; Xiaoxia Li; Yingnan Chi; Changwen Hu

doi:10.1039/d0cc06277d

Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

Ni Zhen
, Jing Dong
, Zhengguo Lin
, Xiaoxia Li
, Yingnan Chi^*
, Changwen Hu

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

Original language	English
Pages (from-to)	13967-13970
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	90
DOIs	https://doi.org/10.1039/d0cc06277d
Publication status	Published - 21 Nov 2020
Externally published	Yes

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title = "Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants",

abstract = "We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new \{Nb23\} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.",

author = "Ni Zhen and Jing Dong and Zhengguo Lin and Xiaoxia Li and Yingnan Chi and Changwen Hu",

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year = "2020",

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doi = "10.1039/d0cc06277d",

language = "English",

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TY - JOUR

T1 - Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

AU - Zhen, Ni

AU - Dong, Jing

AU - Lin, Zhengguo

AU - Li, Xiaoxia

AU - Chi, Yingnan

AU - Hu, Changwen

PY - 2020/11/21

Y1 - 2020/11/21

N2 - We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

AB - We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

UR - https://www.scopus.com/pages/publications/85096152771

U2 - 10.1039/d0cc06277d

DO - 10.1039/d0cc06277d

M3 - Article

C2 - 33057482

AN - SCOPUS:85096152771

SN - 1359-7345

VL - 56

SP - 13967

EP - 13970

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

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