Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer

Xiaobang Zhang; Xiaomei Wei; Sheng Li Huang; Guo Yu Yang

doi:10.1002/asia.202100482

Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)₃ photosensitizer

Xiaobang Zhang
, Xiaomei Wei
, Sheng Li Huang^*
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)₃ photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

Original language	English
Pages (from-to)	2031-2034
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	16
Issue number	15
DOIs	https://doi.org/10.1002/asia.202100482
Publication status	Published - 2 Aug 2021

Keywords

Rare-earth metal-organic frameworks
Ru(N^N) photosensitizer
photocatalysis
sulfide oxidation

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10.1002/asia.202100482

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title = "Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer",

abstract = "Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N\textasciicircum{}N site, and the Ru(N\textasciicircum{}N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.",

keywords = "Rare-earth metal-organic frameworks, Ru(N\textasciicircum{}N) photosensitizer, photocatalysis, sulfide oxidation",

author = "Xiaobang Zhang and Xiaomei Wei and Huang, \{Sheng Li\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2021",

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doi = "10.1002/asia.202100482",

language = "English",

volume = "16",

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journal = "Chemistry - An Asian Journal",

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TY - JOUR

T1 - Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer

AU - Zhang, Xiaobang

AU - Wei, Xiaomei

AU - Huang, Sheng Li

AU - Yang, Guo Yu

PY - 2021/8/2

Y1 - 2021/8/2

N2 - Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

AB - Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.

KW - Rare-earth metal-organic frameworks

KW - Ru(N^N) photosensitizer

KW - photocatalysis

KW - sulfide oxidation

UR - https://www.scopus.com/pages/publications/85111921367

U2 - 10.1002/asia.202100482

DO - 10.1002/asia.202100482

M3 - Article

C2 - 34180132

AN - SCOPUS:85111921367

SN - 1861-4728

VL - 16

SP - 2031

EP - 2034

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 15

ER -

Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)₃ photosensitizer

Abstract

Keywords

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