Selective nitration of thiacalix[4]arene and an investigation of its acid-base properties with a chemometric method

Xiaojun Hu; Huijie Shi; Xianfa Shi; Zhongliang Zhu; Qiuhong Sun; Yong Li; Haijun Yang

doi:10.1246/bcsj.78.138

Selective nitration of thiacalix[4]arene and an investigation of its acid-base properties with a chemometric method

Xiaojun Hu
, Huijie Shi
, Xianfa Shi^*
, Zhongliang Zhu
, Qiuhong Sun
, Yong Li
, Haijun Yang

^*Corresponding author for this work

Tongji University
Tsinghua University
Hebei University of Science and Technology

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The selective dinitro-substituted derivative of thiacalix[4]arene was synthesized by a three-step route and characterized. Its acid-base properties in a water solution were studied by UV-vis spectroscopy. Its four pK_a values were determined by Target Testing Factor Analysis (TTFA).

Original language	English
Pages (from-to)	138-141
Number of pages	4
Journal	Bulletin of the Chemical Society of Japan
Volume	78
Issue number	1
DOIs	https://doi.org/10.1246/bcsj.78.138
Publication status	Published - Jan 2005
Externally published	Yes

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title = "Selective nitration of thiacalix[4]arene and an investigation of its acid-base properties with a chemometric method",

abstract = "The selective dinitro-substituted derivative of thiacalix[4]arene was synthesized by a three-step route and characterized. Its acid-base properties in a water solution were studied by UV-vis spectroscopy. Its four pKa values were determined by Target Testing Factor Analysis (TTFA).",

author = "Xiaojun Hu and Huijie Shi and Xianfa Shi and Zhongliang Zhu and Qiuhong Sun and Yong Li and Haijun Yang",

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AU - Hu, Xiaojun

AU - Shi, Huijie

AU - Shi, Xianfa

AU - Zhu, Zhongliang

AU - Sun, Qiuhong

AU - Li, Yong

AU - Yang, Haijun

PY - 2005/1

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N2 - The selective dinitro-substituted derivative of thiacalix[4]arene was synthesized by a three-step route and characterized. Its acid-base properties in a water solution were studied by UV-vis spectroscopy. Its four pKa values were determined by Target Testing Factor Analysis (TTFA).

AB - The selective dinitro-substituted derivative of thiacalix[4]arene was synthesized by a three-step route and characterized. Its acid-base properties in a water solution were studied by UV-vis spectroscopy. Its four pKa values were determined by Target Testing Factor Analysis (TTFA).

UR - https://www.scopus.com/pages/publications/13444279938

U2 - 10.1246/bcsj.78.138

DO - 10.1246/bcsj.78.138

M3 - Article

AN - SCOPUS:13444279938

SN - 0009-2673

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EP - 141

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 1

ER -

Selective nitration of thiacalix[4]arene and an investigation of its acid-base properties with a chemometric method

Abstract

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