Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng; Yanhua Wang; Yicheng Xu; Ying Song; Jiaqi Zhao; Jingyang Jiang; Zilin Jin

doi:10.1016/S1872-2067(11)60371-9

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng, Yanhua Wang^*, Yicheng Xu, Ying Song, Jiaqi Zhao, Jingyang Jiang, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH₃(OCH₂CH₂)₁₆ N⁺Et₃] [CH₃SO₃^-] (IL_PEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99% and 91%, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

Original language	English
Pages (from-to)	402-406
Number of pages	5
Journal	Chinese Journal of Catalysis
Volume	33
Issue number	3
DOIs	https://doi.org/10.1016/S1872-2067(11)60371-9
Publication status	Published - Mar 2012
Externally published	Yes

Keywords

Hydroformylation
Nanoparticle
Olefin
Rhodium
Thermoregulated ionic liquid/organic biphasic system

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10.1016/S1872-2067(11)60371-9

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title = "Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system",

abstract = "Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2)16 N+Et3] [CH3SO3-] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99% and 91%, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.",

keywords = "Hydroformylation, Nanoparticle, Olefin, Rhodium, Thermoregulated ionic liquid/organic biphasic system",

author = "Yan Zeng and Yanhua Wang and Yicheng Xu and Ying Song and Jiaqi Zhao and Jingyang Jiang and Zilin Jin",

year = "2012",

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doi = "10.1016/S1872-2067(11)60371-9",

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journal = "Chinese Journal of Catalysis",

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T1 - Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

AU - Zeng, Yan

AU - Wang, Yanhua

AU - Xu, Yicheng

AU - Song, Ying

AU - Zhao, Jiaqi

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2012/3

Y1 - 2012/3

N2 - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2)16 N+Et3] [CH3SO3-] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99% and 91%, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

AB - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2)16 N+Et3] [CH3SO3-] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99% and 91%, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

KW - Hydroformylation

KW - Nanoparticle

KW - Olefin

KW - Rhodium

KW - Thermoregulated ionic liquid/organic biphasic system

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DO - 10.1016/S1872-2067(11)60371-9

M3 - Article

AN - SCOPUS:84860317450

SN - 1872-2067

VL - 33

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JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 3

ER -

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Abstract

Keywords

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