Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng; Yanhua Wang; Yicheng Xu; Ying Song; Jiaqi Zhao; Jingyang Jiang; Zilin Jin

doi:10.1016/S1872-2067(11)60371-9

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng, Yanhua Wang^*, Yicheng Xu, Ying Song, Jiaqi Zhao, Jingyang Jiang, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH₃(OCH₂CH₂) ₁₆N⁺Et₃][CH₃SO₃ ^-] (IL_PEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

Original language	English
Pages (from-to)	402-406
Number of pages	5
Journal	Chinese Journal of Catalysis
Volume	33
Issue number	2-3
DOIs	https://doi.org/10.1016/S1872-2067(11)60371-9
Publication status	Published - 2012
Externally published	Yes

Keywords

hydroformylation
nanoparticle
olefin
rhodium
thermoregulated ionic liquid/organic biphasic system

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10.1016/S1872-2067(11)60371-9

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title = "Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system",

abstract = "Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.",

keywords = "hydroformylation, nanoparticle, olefin, rhodium, thermoregulated ionic liquid/organic biphasic system",

author = "Yan Zeng and Yanhua Wang and Yicheng Xu and Ying Song and Jiaqi Zhao and Jingyang Jiang and Zilin Jin",

year = "2012",

doi = "10.1016/S1872-2067(11)60371-9",

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TY - JOUR

T1 - Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

AU - Zeng, Yan

AU - Wang, Yanhua

AU - Xu, Yicheng

AU - Song, Ying

AU - Zhao, Jiaqi

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2012

Y1 - 2012

N2 - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

AB - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

KW - hydroformylation

KW - nanoparticle

KW - olefin

KW - rhodium

KW - thermoregulated ionic liquid/organic biphasic system

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U2 - 10.1016/S1872-2067(11)60371-9

DO - 10.1016/S1872-2067(11)60371-9

M3 - Article

AN - SCOPUS:84859782226

SN - 1872-2067

VL - 33

SP - 402

EP - 406

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 2-3

ER -

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Abstract

Keywords

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