Rh nanoparticle catalyzed hydrogenation of olefins in thermoregulated ionic liquid and organic biphase system

Yan Zeng; Yanhua Wang; Jingyang Jiang; Zilin Jin

doi:10.1016/j.catcom.2011.11.037

Rh nanoparticle catalyzed hydrogenation of olefins in thermoregulated ionic liquid and organic biphase system

Yan Zeng
, Yanhua Wang^*
, Jingyang Jiang
, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Rh nanoparticle catalyzed hydrogenation of olefins in a biphase system composed of [CH ₃(OCH ₂CH ₂) ₁₆N ⁺Et ₃][CH ₃SO ₃ ^-] (IL _PEG750) ionic liquid and organic solvent allows for not only a highly efficient homogeneous catalytic reaction, but also an easy separation and reuse of catalyst attributed to the thermoregulated phase-transition property of the IL _PEG750 and organic biphase system. Under the optimized conditions, various alkenes could be hydrogenated to the corresponding alkanes as the sole product with 100% conversion. The Rh nanoparticles can be recovered by simple phase separation and reused for nine times without evident loss of activity.

Original language	English
Pages (from-to)	70-73
Number of pages	4
Journal	Catalysis Communications
Volume	19
DOIs	https://doi.org/10.1016/j.catcom.2011.11.037
Publication status	Published - Mar 2012
Externally published	Yes

Keywords

Hydrogenation
Nanoparticles
Olefin
Rhodium catalyst
Thermoregulated ionic liquid and organic biphase system

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10.1016/j.catcom.2011.11.037

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@article{b98e71b52c354e588210d432c97e1b7c,

title = "Rh nanoparticle catalyzed hydrogenation of olefins in thermoregulated ionic liquid and organic biphase system",

abstract = "Rh nanoparticle catalyzed hydrogenation of olefins in a biphase system composed of [CH 3(OCH 2CH 2) 16N +Et 3][CH 3SO 3 -] (IL PEG750) ionic liquid and organic solvent allows for not only a highly efficient homogeneous catalytic reaction, but also an easy separation and reuse of catalyst attributed to the thermoregulated phase-transition property of the IL PEG750 and organic biphase system. Under the optimized conditions, various alkenes could be hydrogenated to the corresponding alkanes as the sole product with 100\% conversion. The Rh nanoparticles can be recovered by simple phase separation and reused for nine times without evident loss of activity.",

keywords = "Hydrogenation, Nanoparticles, Olefin, Rhodium catalyst, Thermoregulated ionic liquid and organic biphase system",

author = "Yan Zeng and Yanhua Wang and Jingyang Jiang and Zilin Jin",

year = "2012",

month = mar,

doi = "10.1016/j.catcom.2011.11.037",

language = "English",

volume = "19",

pages = "70--73",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Rh nanoparticle catalyzed hydrogenation of olefins in thermoregulated ionic liquid and organic biphase system

AU - Zeng, Yan

AU - Wang, Yanhua

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2012/3

Y1 - 2012/3

N2 - Rh nanoparticle catalyzed hydrogenation of olefins in a biphase system composed of [CH 3(OCH 2CH 2) 16N +Et 3][CH 3SO 3 -] (IL PEG750) ionic liquid and organic solvent allows for not only a highly efficient homogeneous catalytic reaction, but also an easy separation and reuse of catalyst attributed to the thermoregulated phase-transition property of the IL PEG750 and organic biphase system. Under the optimized conditions, various alkenes could be hydrogenated to the corresponding alkanes as the sole product with 100% conversion. The Rh nanoparticles can be recovered by simple phase separation and reused for nine times without evident loss of activity.

AB - Rh nanoparticle catalyzed hydrogenation of olefins in a biphase system composed of [CH 3(OCH 2CH 2) 16N +Et 3][CH 3SO 3 -] (IL PEG750) ionic liquid and organic solvent allows for not only a highly efficient homogeneous catalytic reaction, but also an easy separation and reuse of catalyst attributed to the thermoregulated phase-transition property of the IL PEG750 and organic biphase system. Under the optimized conditions, various alkenes could be hydrogenated to the corresponding alkanes as the sole product with 100% conversion. The Rh nanoparticles can be recovered by simple phase separation and reused for nine times without evident loss of activity.

KW - Hydrogenation

KW - Nanoparticles

KW - Olefin

KW - Rhodium catalyst

KW - Thermoregulated ionic liquid and organic biphase system

UR - https://www.scopus.com/pages/publications/84862776521

U2 - 10.1016/j.catcom.2011.11.037

DO - 10.1016/j.catcom.2011.11.037

M3 - Article

AN - SCOPUS:84862776521

SN - 1566-7367

VL - 19

SP - 70

EP - 73

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Rh nanoparticle catalyzed hydrogenation of olefins in thermoregulated ionic liquid and organic biphase system

Abstract

Keywords

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