Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system

Yicheng Xu; Yanhua Wang; Kaoxue Li; Mingming Niu; Yan Zeng; Jingyang Jiang; Zilin Jin

doi:10.1166/jnn.2013.7573

Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system

Yicheng Xu, Yanhua Wang^*, Kaoxue Li, Mingming Niu, Yan Zeng, Jingyang Jiang, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH₃(OCH₂ CH₂)₂₂N+Et ₃][CH₃SO^-₃ ] (abbreviated as IL _PEG1000) containing IL_PEG1000-stabilized Rh nanoparticles and organic solvent, which allows for not only highly efficient homogeneous reaction but also an easy biphasic separation, was applied to the hydroaminomethylation of 1-octene for the first time. Under the optimized conditions, the conversion of 1-octene and the amine selectivity were 100% and 90%, respectively. After reaction, the Rh nanoparticle catalyst could be easily separated by simple decantation and reused for four times without evident loss in activity.

Original language	English
Pages (from-to)	5048-5052
Number of pages	5
Journal	Journal of Nanoscience and Nanotechnology
Volume	13
Issue number	7
DOIs	https://doi.org/10.1166/jnn.2013.7573
Publication status	Published - Jul 2013
Externally published	Yes

Keywords

1-Octene
Catalyst Recycling
Hydroaminomethylation
Rh Nanoparticle
Thermoregulated Ionic Liquid and Organic Biphasic System

Access to Document

10.1166/jnn.2013.7573

Cite this

@article{41ef5bae03a5425784ee607c97ecf634,

title = "Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system",

abstract = "Thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH3(OCH2 CH2)22N+Et 3][CH3SO-3 ] (abbreviated as IL PEG1000) containing ILPEG1000-stabilized Rh nanoparticles and organic solvent, which allows for not only highly efficient homogeneous reaction but also an easy biphasic separation, was applied to the hydroaminomethylation of 1-octene for the first time. Under the optimized conditions, the conversion of 1-octene and the amine selectivity were 100% and 90%, respectively. After reaction, the Rh nanoparticle catalyst could be easily separated by simple decantation and reused for four times without evident loss in activity.",

keywords = "1-Octene, Catalyst Recycling, Hydroaminomethylation, Rh Nanoparticle, Thermoregulated Ionic Liquid and Organic Biphasic System",

author = "Yicheng Xu and Yanhua Wang and Kaoxue Li and Mingming Niu and Yan Zeng and Jingyang Jiang and Zilin Jin",

year = "2013",

month = jul,

doi = "10.1166/jnn.2013.7573",

language = "English",

volume = "13",

pages = "5048--5052",

journal = "Journal of Nanoscience and Nanotechnology",

issn = "1533-4880",

publisher = "American Scientific Publishers",

number = "7",

}

TY - JOUR

T1 - Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system

AU - Xu, Yicheng

AU - Wang, Yanhua

AU - Li, Kaoxue

AU - Niu, Mingming

AU - Zeng, Yan

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2013/7

Y1 - 2013/7

N2 - Thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH3(OCH2 CH2)22N+Et 3][CH3SO-3 ] (abbreviated as IL PEG1000) containing ILPEG1000-stabilized Rh nanoparticles and organic solvent, which allows for not only highly efficient homogeneous reaction but also an easy biphasic separation, was applied to the hydroaminomethylation of 1-octene for the first time. Under the optimized conditions, the conversion of 1-octene and the amine selectivity were 100% and 90%, respectively. After reaction, the Rh nanoparticle catalyst could be easily separated by simple decantation and reused for four times without evident loss in activity.

AB - Thermoregulated ionic liquid and organic biphasic system composed of ionic liquid [CH3(OCH2 CH2)22N+Et 3][CH3SO-3 ] (abbreviated as IL PEG1000) containing ILPEG1000-stabilized Rh nanoparticles and organic solvent, which allows for not only highly efficient homogeneous reaction but also an easy biphasic separation, was applied to the hydroaminomethylation of 1-octene for the first time. Under the optimized conditions, the conversion of 1-octene and the amine selectivity were 100% and 90%, respectively. After reaction, the Rh nanoparticle catalyst could be easily separated by simple decantation and reused for four times without evident loss in activity.

KW - 1-Octene

KW - Catalyst Recycling

KW - Hydroaminomethylation

KW - Rh Nanoparticle

KW - Thermoregulated Ionic Liquid and Organic Biphasic System

UR - http://www.scopus.com/inward/record.url?scp=84880535962&partnerID=8YFLogxK

U2 - 10.1166/jnn.2013.7573

DO - 10.1166/jnn.2013.7573

M3 - Article

C2 - 23901529

AN - SCOPUS:84880535962

SN - 1533-4880

VL - 13

SP - 5048

EP - 5052

JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 7

ER -

Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this