Reviews of Fiber-Reinforced Phenolic Resin-Based Thermal Protection Materials for Aircraft

As advancements in aerospace technology continue, reentry conditions pose increasingly rigorous requirements for thermal protection materials. Among these, fiber-reinforced phenolic resin composites have drawn substantial interest for their robust thermal insulation capabilities and enhanced ablation resistance, mechanical strength, and long-term reliability. This paper provides a comprehensive review of recent developments in fiber-reinforced phenolic resin composites, examining factors such as resin density, nanopore size within the matrix, resin cross-linking density, fiber–resin interfacial bonding, fiber length, fiber crystallization degree, and fiber weave structures that collectively influence composite performance. The typical applications of these composites in ultrahigh-speed aircraft are also discussed. Furthermore, the paper offers recommendations for future advancements focusing on optimizing mechanical, ablative, and insulation properties to meet the multifunctional demands of thermal protection materials.