Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework

Fu Ling Liu; Dong Li; Li Jie Su; Jun Tao

doi:10.1039/c7dt04205a

Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework

Fu Ling Liu, Dong Li, Li Jie Su, Jun Tao^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Xiamen University

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [Fe^II(Hbpt)Pt(CN)₄]·1/2Hbpt·1/2CH₃OH·5/2H₂O [1, Hbpt = 4,4′-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS^1.00 ↔ HS^0.75LS^0.25 ↔ HS^0.5LS^0.5 ↔ HS^0.25LS^0.75.

Original language	English
Pages (from-to)	1407-1411
Number of pages	5
Journal	Dalton Transactions
Volume	47
Issue number	5
DOIs	https://doi.org/10.1039/c7dt04205a
Publication status	Published - 2018

Access to Document

10.1039/c7dt04205a

Cite this

@article{7a7e3c2cce224e7e9082c75048542936,

title = "Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework",

abstract = "A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [FeII(Hbpt)Pt(CN)4]·1/2Hbpt·1/2CH3OH·5/2H2O [1, Hbpt = 4,4′-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.",

author = "Liu, {Fu Ling} and Dong Li and Su, {Li Jie} and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c7dt04205a",

language = "English",

volume = "47",

pages = "1407--1411",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework

AU - Liu, Fu Ling

AU - Li, Dong

AU - Su, Li Jie

AU - Tao, Jun

PY - 2018

Y1 - 2018

N2 - A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [FeII(Hbpt)Pt(CN)4]·1/2Hbpt·1/2CH3OH·5/2H2O [1, Hbpt = 4,4′-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

AB - A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [FeII(Hbpt)Pt(CN)4]·1/2Hbpt·1/2CH3OH·5/2H2O [1, Hbpt = 4,4′-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

UR - http://www.scopus.com/inward/record.url?scp=85041336963&partnerID=8YFLogxK

U2 - 10.1039/c7dt04205a

DO - 10.1039/c7dt04205a

M3 - Article

C2 - 29327755

AN - SCOPUS:85041336963

SN - 1477-9226

VL - 47

SP - 1407

EP - 1411

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework

Abstract

Access to Document

Other files and links

Fingerprint

Cite this