Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands

Tingwei Wang; Chao Zhang; Zujia Lu; Baolong Kuang; Zhiming Xie; Zhenxin Yi; Yan Li; Jianguo Zhang

doi:10.1039/d3qi00833a

Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands

Tingwei Wang
, Chao Zhang
, Zujia Lu
, Baolong Kuang
, Zhiming Xie
, Zhenxin Yi
, Yan Li
, Jianguo Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In order to resolve the conflict between mechanical sensitivity and explosive performance, we utilized a retro-synthesis approach to design and synthesize the ligand 1H-imidazole-4-carbohydrazide (4-IMCA) and the complex Cu(4-IMCA)₂(ClO₄)₂ (ECC-1). The structure of the product was confirmed by single-crystal X-ray diffraction, IR and elemental analysis. The results showed that the physicochemical stability of ECC-1 was improved, including thermal stability (T_d = 200 °C), mechanical sensitivity (IS = 3 J, FS = 7 N), and explosive performance. Moreover, laser ignition (P = 22 W, τ = 3 ms, E = 66 mJ) and lead plate damage tests showed that the detonation ability of ECC-1 was not compromised.

Original language	English
Pages (from-to)	4773-4779
Number of pages	7
Journal	Inorganic Chemistry Frontiers
Volume	10
Issue number	16
DOIs	https://doi.org/10.1039/d3qi00833a
Publication status	Published - 8 Jul 2023

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title = "Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands",

abstract = "In order to resolve the conflict between mechanical sensitivity and explosive performance, we utilized a retro-synthesis approach to design and synthesize the ligand 1H-imidazole-4-carbohydrazide (4-IMCA) and the complex Cu(4-IMCA)2(ClO4)2 (ECC-1). The structure of the product was confirmed by single-crystal X-ray diffraction, IR and elemental analysis. The results showed that the physicochemical stability of ECC-1 was improved, including thermal stability (Td = 200 °C), mechanical sensitivity (IS = 3 J, FS = 7 N), and explosive performance. Moreover, laser ignition (P = 22 W, τ = 3 ms, E = 66 mJ) and lead plate damage tests showed that the detonation ability of ECC-1 was not compromised.",

author = "Tingwei Wang and Chao Zhang and Zujia Lu and Baolong Kuang and Zhiming Xie and Zhenxin Yi and Yan Li and Jianguo Zhang",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = jul,

day = "8",

doi = "10.1039/d3qi00833a",

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volume = "10",

pages = "4773--4779",

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}

TY - JOUR

T1 - Regulation of stability and detonation performance

T2 - preparation of coordination compounds by using isomeric ligands

AU - Wang, Tingwei

AU - Zhang, Chao

AU - Lu, Zujia

AU - Kuang, Baolong

AU - Xie, Zhiming

AU - Yi, Zhenxin

AU - Li, Yan

AU - Zhang, Jianguo

PY - 2023/7/8

Y1 - 2023/7/8

N2 - In order to resolve the conflict between mechanical sensitivity and explosive performance, we utilized a retro-synthesis approach to design and synthesize the ligand 1H-imidazole-4-carbohydrazide (4-IMCA) and the complex Cu(4-IMCA)2(ClO4)2 (ECC-1). The structure of the product was confirmed by single-crystal X-ray diffraction, IR and elemental analysis. The results showed that the physicochemical stability of ECC-1 was improved, including thermal stability (Td = 200 °C), mechanical sensitivity (IS = 3 J, FS = 7 N), and explosive performance. Moreover, laser ignition (P = 22 W, τ = 3 ms, E = 66 mJ) and lead plate damage tests showed that the detonation ability of ECC-1 was not compromised.

AB - In order to resolve the conflict between mechanical sensitivity and explosive performance, we utilized a retro-synthesis approach to design and synthesize the ligand 1H-imidazole-4-carbohydrazide (4-IMCA) and the complex Cu(4-IMCA)2(ClO4)2 (ECC-1). The structure of the product was confirmed by single-crystal X-ray diffraction, IR and elemental analysis. The results showed that the physicochemical stability of ECC-1 was improved, including thermal stability (Td = 200 °C), mechanical sensitivity (IS = 3 J, FS = 7 N), and explosive performance. Moreover, laser ignition (P = 22 W, τ = 3 ms, E = 66 mJ) and lead plate damage tests showed that the detonation ability of ECC-1 was not compromised.

UR - https://www.scopus.com/pages/publications/85166099068

U2 - 10.1039/d3qi00833a

DO - 10.1039/d3qi00833a

M3 - Article

AN - SCOPUS:85166099068

SN - 2052-1545

VL - 10

SP - 4773

EP - 4779

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 16

ER -

Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands

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