TY - JOUR
T1 - Regulating the microstructure and hydrophilicity of cellulose nanofibers using taurine and the application in humidity sensor and actuator
AU - Li, Zhimao
AU - Song, Kaixu
AU - Wu, Qian
AU - Wang, Can
AU - Jiang, Jinlong
AU - Ye, Xinming
AU - Ma, Siyuan
AU - Li, Jie
AU - Shao, Ziqiang
N1 - Publisher Copyright:
© 2024
PY - 2024/10/15
Y1 - 2024/10/15
N2 - Exploring the interrelationships between microstructure, hydrophilicity, humidity response, and material stability through molecular structure design and low-cost preparation, and manufacturing sensing and driving materials with a perfect balance between structures and properties is crucial for biomimetic robots and intelligent devices. Herein, inspired by the capillary phenomenon, the cellulose nanofiber (CNF) was grafted by using taurine to form the “micro cilia” microstructure on its surface (CNF-TAU). By controlling the cilia density and symmetry, the hydrophilicity of the materials was adjusted, and the water was allowed to quickly separate from the inside of the materials, which led to improving the humidity sensitivity and stability of materials. Concretely, compared with CNF, the puncture load, tearing strength, and elongation at break of the CNF-TAU-1.0 were improved by 11.95 times, 2.16 times, and 15.6 %, respectively, and excellent tensile strength was presented. Moreover, the hydrophilicity of CNF-TAU was first weakened and then enhanced with TAU content increasing. At last, the CNF-TAU-1.0 (WCA 55.43°) was selected and blended with single-layer graphene oxide (GO) to prepare CNF-TAU/GO composite films by vacuum filtration. The results indicated that the composite film had excellent mechanical (room and high humidity), humidity responsiveness, and humidity gradient-driven properties. In detail, the CNF-TAU/GO-10 % composite film had the generated stable induced voltage (68.4 mV), the fast response/recovery time (0.3 s/0.9 s), the large max. bending angle (178.4°), and the drive cycle stability (1000 cycles). Moreover, the composite film could be applied to produce biomimetic soft robots, such as human fingers and butterfly-shaped robots.
AB - Exploring the interrelationships between microstructure, hydrophilicity, humidity response, and material stability through molecular structure design and low-cost preparation, and manufacturing sensing and driving materials with a perfect balance between structures and properties is crucial for biomimetic robots and intelligent devices. Herein, inspired by the capillary phenomenon, the cellulose nanofiber (CNF) was grafted by using taurine to form the “micro cilia” microstructure on its surface (CNF-TAU). By controlling the cilia density and symmetry, the hydrophilicity of the materials was adjusted, and the water was allowed to quickly separate from the inside of the materials, which led to improving the humidity sensitivity and stability of materials. Concretely, compared with CNF, the puncture load, tearing strength, and elongation at break of the CNF-TAU-1.0 were improved by 11.95 times, 2.16 times, and 15.6 %, respectively, and excellent tensile strength was presented. Moreover, the hydrophilicity of CNF-TAU was first weakened and then enhanced with TAU content increasing. At last, the CNF-TAU-1.0 (WCA 55.43°) was selected and blended with single-layer graphene oxide (GO) to prepare CNF-TAU/GO composite films by vacuum filtration. The results indicated that the composite film had excellent mechanical (room and high humidity), humidity responsiveness, and humidity gradient-driven properties. In detail, the CNF-TAU/GO-10 % composite film had the generated stable induced voltage (68.4 mV), the fast response/recovery time (0.3 s/0.9 s), the large max. bending angle (178.4°), and the drive cycle stability (1000 cycles). Moreover, the composite film could be applied to produce biomimetic soft robots, such as human fingers and butterfly-shaped robots.
KW - Humidity responsiveness
KW - Hydrophobicity
KW - Microstructure
KW - Wearable devices
UR - http://www.scopus.com/inward/record.url?scp=85202166745&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2024.154923
DO - 10.1016/j.cej.2024.154923
M3 - Article
AN - SCOPUS:85202166745
SN - 1385-8947
VL - 498
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
M1 - 154923
ER -