Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene in ionic liquids

Zi Hui Meng; Feng Min Yang; Qing Xia Li; Zhi Ming Zhou

doi:10.3969/j.issn.1006-9941.2009.06.025

Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene in ionic liquids

Zi Hui Meng^*, Feng Min Yang, Qing Xia Li, Zhi Ming Zhou

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) in five kinds of ionic liquids, including 3-ethyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium hexafluorophosphorus, 3-hexyl-1-methylimidazolium bromine and 3-butyl-1-methylimidazolium chloride ([Bmim] Cl) was investigated. TATB can be dissolved in [Bmim] Cl, and the thermal stability of TATB improved after recrystalization in the ionic liquid was also investigated. The exothermic temperature of the recrystalized TATB (375°C) which is higher than that of raw TATB (363°C) indicats that the stability of recrystalized TATB is improved.

Original language	English
Pages (from-to)	753-754
Number of pages	2
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	17
Issue number	6
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2009.06.025
Publication status	Published - Dec 2009

Keywords

1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB)
Ionic liquid
Organic chemistry
Recrystallization

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10.3969/j.issn.1006-9941.2009.06.025

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title = "Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene in ionic liquids",

abstract = "Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) in five kinds of ionic liquids, including 3-ethyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium hexafluorophosphorus, 3-hexyl-1-methylimidazolium bromine and 3-butyl-1-methylimidazolium chloride ([Bmim] Cl) was investigated. TATB can be dissolved in [Bmim] Cl, and the thermal stability of TATB improved after recrystalization in the ionic liquid was also investigated. The exothermic temperature of the recrystalized TATB (375°C) which is higher than that of raw TATB (363°C) indicats that the stability of recrystalized TATB is improved.",

keywords = "1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB), Ionic liquid, Organic chemistry, Recrystallization",

author = "Meng, {Zi Hui} and Yang, {Feng Min} and Li, {Qing Xia} and Zhou, {Zhi Ming}",

year = "2009",

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doi = "10.3969/j.issn.1006-9941.2009.06.025",

language = "English",

volume = "17",

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journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

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T1 - Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene in ionic liquids

AU - Meng, Zi Hui

AU - Yang, Feng Min

AU - Li, Qing Xia

AU - Zhou, Zhi Ming

PY - 2009/12

Y1 - 2009/12

N2 - Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) in five kinds of ionic liquids, including 3-ethyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium hexafluorophosphorus, 3-hexyl-1-methylimidazolium bromine and 3-butyl-1-methylimidazolium chloride ([Bmim] Cl) was investigated. TATB can be dissolved in [Bmim] Cl, and the thermal stability of TATB improved after recrystalization in the ionic liquid was also investigated. The exothermic temperature of the recrystalized TATB (375°C) which is higher than that of raw TATB (363°C) indicats that the stability of recrystalized TATB is improved.

AB - Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) in five kinds of ionic liquids, including 3-ethyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium tetrafluoroborate, 3-butyl-1-methylimidazolium hexafluorophosphorus, 3-hexyl-1-methylimidazolium bromine and 3-butyl-1-methylimidazolium chloride ([Bmim] Cl) was investigated. TATB can be dissolved in [Bmim] Cl, and the thermal stability of TATB improved after recrystalization in the ionic liquid was also investigated. The exothermic temperature of the recrystalized TATB (375°C) which is higher than that of raw TATB (363°C) indicats that the stability of recrystalized TATB is improved.

KW - 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB)

KW - Ionic liquid

KW - Organic chemistry

KW - Recrystallization

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U2 - 10.3969/j.issn.1006-9941.2009.06.025

DO - 10.3969/j.issn.1006-9941.2009.06.025

M3 - Article

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JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

Recrystallization of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene in ionic liquids

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Keywords

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